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The impact of phase changes, alloying and segregation in supported RhPd catalysts during selective NO reduction by H2

The impact of phase changes, alloying and segregation in supported RhPd catalysts during selective NO reduction by H2
The impact of phase changes, alloying and segregation in supported RhPd catalysts during selective NO reduction by H2
Illuminating complexity: Time resolved, microreactor-based, EDE/mass spectrometry (EDE = energy dispersive extended X-ray absorption fine structure) was used to probe the behaviour of both Rh and Pd components of alloyed nanoparticles during NO reduction by H2. The surface enrichment in Pd is shown to curtail the rapid oxidation of the Rh component by NO and leads to a promotion of NO reduction.
alloys, heterogeneous catalysis, palladium, rhodium, structure-activityrelationships, x-ray absorption spectroscopyenergy-dispersive exafs, in-situ, precursors
1439-4235
1056-1058
Newton, Mark A.
73aab2af-4641-47f3-89ad-3b7d3026164f
Jyoti, Bhrat
9e00e347-0864-48fa-9bb8-f44f98161fd0
Dent, Andrew J.
24c2a218-cb0e-4193-af0b-3ff1dc42b552
Diaz-Moreno, Sofia
4e280df3-7f62-4280-8058-2803c740ae00
Fiddy, Steven G.
f6c255cf-6aa1-4798-85ca-1a2ccdaa1186
Evans, John
05890433-0155-49fe-a65d-38c90ea25c69
Newton, Mark A.
73aab2af-4641-47f3-89ad-3b7d3026164f
Jyoti, Bhrat
9e00e347-0864-48fa-9bb8-f44f98161fd0
Dent, Andrew J.
24c2a218-cb0e-4193-af0b-3ff1dc42b552
Diaz-Moreno, Sofia
4e280df3-7f62-4280-8058-2803c740ae00
Fiddy, Steven G.
f6c255cf-6aa1-4798-85ca-1a2ccdaa1186
Evans, John
05890433-0155-49fe-a65d-38c90ea25c69

Newton, Mark A., Jyoti, Bhrat, Dent, Andrew J., Diaz-Moreno, Sofia, Fiddy, Steven G. and Evans, John (2004) The impact of phase changes, alloying and segregation in supported RhPd catalysts during selective NO reduction by H2. ChemPhysChem, 5 (7), 1056-1058. (doi:10.1002/cphc.200400204).

Record type: Article

Abstract

Illuminating complexity: Time resolved, microreactor-based, EDE/mass spectrometry (EDE = energy dispersive extended X-ray absorption fine structure) was used to probe the behaviour of both Rh and Pd components of alloyed nanoparticles during NO reduction by H2. The surface enrichment in Pd is shown to curtail the rapid oxidation of the Rh component by NO and leads to a promotion of NO reduction.

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More information

Published date: 19 July 2004
Keywords: alloys, heterogeneous catalysis, palladium, rhodium, structure-activityrelationships, x-ray absorption spectroscopyenergy-dispersive exafs, in-situ, precursors

Identifiers

Local EPrints ID: 20294
URI: http://eprints.soton.ac.uk/id/eprint/20294
ISSN: 1439-4235
PURE UUID: 2da0c901-fd26-4f7b-91e1-2dcec318d625

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Date deposited: 20 Feb 2006
Last modified: 15 Mar 2024 06:23

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Contributors

Author: Mark A. Newton
Author: Bhrat Jyoti
Author: Andrew J. Dent
Author: Sofia Diaz-Moreno
Author: Steven G. Fiddy
Author: John Evans

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