The University of Southampton
×
Filter your search:
University of Southampton Institutional Repository

Insertion of (E)-(1,2-dihalovinyl)lithium and (2-haloethynyl)lithium into zirconacycles

Insertion of (E)-(1,2-dihalovinyl)lithium and (2-haloethynyl)lithium into zirconacycles
Insertion of (E)-(1,2-dihalovinyl)lithium and (2-haloethynyl)lithium into zirconacycles
Insertion of (E)-(1,2-dihalovinyl)lithium into zirconacyclopentenes was followed by elimination of halide to afford an alkyne which inserts intramolecularly into the resulting carbon-zirconocenium bond to give a methylenecyclopentene, whereas insertion of (2-haloethynyl)lithium gives the same product via a zirconocene alkenylidene.
cyclization, derivatives
1359-7345
1214-1215
Norton, David
4c63fcf9-0fc8-4623-b414-443d4658bbed
Whitby, Richard J.
45632236-ab00-4ad0-a02d-6209043e818b
Griffen, Ed
0a8546b3-ebb1-44f4-8410-53730d606db5
Norton, David
4c63fcf9-0fc8-4623-b414-443d4658bbed
Whitby, Richard J.
45632236-ab00-4ad0-a02d-6209043e818b
Griffen, Ed
0a8546b3-ebb1-44f4-8410-53730d606db5

Norton, David, Whitby, Richard J. and Griffen, Ed (2004) Insertion of (E)-(1,2-dihalovinyl)lithium and (2-haloethynyl)lithium into zirconacycles. Chemical Communications, (10), 1214-1215. (doi:10.1039/b403337j).

Record type: Article

Abstract

Insertion of (E)-(1,2-dihalovinyl)lithium into zirconacyclopentenes was followed by elimination of halide to afford an alkyne which inserts intramolecularly into the resulting carbon-zirconocenium bond to give a methylenecyclopentene, whereas insertion of (2-haloethynyl)lithium gives the same product via a zirconocene alkenylidene.

This record has no associated files available for download.

More information

Published date: 21 May 2004
Additional Information: ChemComm
Keywords: cyclization, derivatives
Learn more about Chemistry research

Identifiers

Local EPrints ID: 20295
URI: http://eprints.soton.ac.uk/id/eprint/20295
DOI: doi:10.1039/b403337j
ISSN: 1359-7345
PURE UUID: b2b33df2-140b-4867-aa3d-5b63678706c2
ORCID for Richard J. Whitby: ORCID iD orcid.org/0000-0002-9891-5502

Catalogue record

Date deposited: 20 Feb 2006
Last modified: 16 Mar 2024 02:33

Export record

Altmetrics

Contributors

Author: David Norton
Author: Richard J. Whitby ORCID iD
Author: Ed Griffen

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Library staff additional information
Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×