Mild mono and double demethylation in dimethylsulfonium substituted ruthenacarborane complexes. A regioselective reaction
Mild mono and double demethylation in dimethylsulfonium substituted ruthenacarborane complexes. A regioselective reaction
Reaction of [RuCl2(eta(6)-C6H6)](2) with [10-(CH3)(2)S-7,8-nido-C2B9H10](-) or [9-(CH3)(2)S-7,8-nido-C2B9H10](-) afforded the expected cationic complexes [Ru(eta(5)-n-(CH3)(2)S-7,8-C2B9H10)(eta(6)-C6H6)](+) (n=10, (1); 9, (3)), but also the unexpected neutral Ru(eta(5)-10-HS-7,8-C2B9H10)(eta(6)-C6H6) (2) or Ru(eta(5)-9-(CH3)S-7,8-C2B9H10)(eta(6)-C6H6) (4) by double and mono demethylation of the (CH3)(2)S moiety, respectively.
sandwich ruthenium complexes, derivatives, metallacarboranes, sulfonium, clusters
2059-2061
Planas, José Giner
98b21b50-1c21-4265-bd3c-67afe28ef652
Viñas, Clara
636b5d2e-fefb-4e83-93df-9615eee8e771
Teixidor, Francesc
d24b81b5-5d82-42ca-bd30-fd9c73d0ee68
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
2004
Planas, José Giner
98b21b50-1c21-4265-bd3c-67afe28ef652
Viñas, Clara
636b5d2e-fefb-4e83-93df-9615eee8e771
Teixidor, Francesc
d24b81b5-5d82-42ca-bd30-fd9c73d0ee68
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Planas, José Giner, Viñas, Clara, Teixidor, Francesc, Hursthouse, Michael B. and Light, Mark E.
(2004)
Mild mono and double demethylation in dimethylsulfonium substituted ruthenacarborane complexes. A regioselective reaction.
Dalton Transactions, (14), .
(doi:10.1039/B408461F).
Abstract
Reaction of [RuCl2(eta(6)-C6H6)](2) with [10-(CH3)(2)S-7,8-nido-C2B9H10](-) or [9-(CH3)(2)S-7,8-nido-C2B9H10](-) afforded the expected cationic complexes [Ru(eta(5)-n-(CH3)(2)S-7,8-C2B9H10)(eta(6)-C6H6)](+) (n=10, (1); 9, (3)), but also the unexpected neutral Ru(eta(5)-10-HS-7,8-C2B9H10)(eta(6)-C6H6) (2) or Ru(eta(5)-9-(CH3)S-7,8-C2B9H10)(eta(6)-C6H6) (4) by double and mono demethylation of the (CH3)(2)S moiety, respectively.
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Published date: 2004
Keywords:
sandwich ruthenium complexes, derivatives, metallacarboranes, sulfonium, clusters
Identifiers
Local EPrints ID: 20305
URI: http://eprints.soton.ac.uk/id/eprint/20305
ISSN: 1477-9226
PURE UUID: b3a410b6-d40d-4bc8-9bef-21744e670679
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Date deposited: 17 Feb 2006
Last modified: 16 Mar 2024 03:04
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Author:
José Giner Planas
Author:
Clara Viñas
Author:
Francesc Teixidor
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