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The CA.M lattice revisited. Gel formation from a linear bis-isocyanuric acid and 2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine

The CA.M lattice revisited. Gel formation from a linear bis-isocyanuric acid and 2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine
The CA.M lattice revisited. Gel formation from a linear bis-isocyanuric acid and 2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine
Five bis(isocyanuric) acid dimers have been prepared and characterised. The introduction of flexible alkyl chains was necessary to aid solubility. On mixing with N,N-bis(4-tert-butyphenyl)melamine in THF followed by slow evaporation, a viscous gel can form which is interpreted as evidence for the assembly of an infinite 2-D hydrogen bonded network.
2-amino-4, 6-bis-(4-tert-butylphenylamino)-1, 3, 5-triazine, cyanuric acid, hydrogen bonding, rosette motifmelamine, assemblies, polymers
0040-4020
6385-6394
Plater, M. J.
3c5273d7-1076-4640-b49e-0d8d7727e4e0
Sinclair, J. P.
7c3bb95f-466d-4149-a4f8-e38cb2fdc1ba
Aiken, S.
4d136549-2d04-4abc-a9a5-4e81d42e99b8
Gelbrich, T.
42309d69-eaf1-4bb7-ba2e-db61f338e370
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Plater, M. J.
3c5273d7-1076-4640-b49e-0d8d7727e4e0
Sinclair, J. P.
7c3bb95f-466d-4149-a4f8-e38cb2fdc1ba
Aiken, S.
4d136549-2d04-4abc-a9a5-4e81d42e99b8
Gelbrich, T.
42309d69-eaf1-4bb7-ba2e-db61f338e370
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Plater, M. J., Sinclair, J. P., Aiken, S., Gelbrich, T. and Hursthouse, M. B. (2004) The CA.M lattice revisited. Gel formation from a linear bis-isocyanuric acid and 2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine. Tetrahedron, 60 (30), 6385-6394. (doi:10.1016/j.tet.2004.03.059).

Record type: Article

Abstract

Five bis(isocyanuric) acid dimers have been prepared and characterised. The introduction of flexible alkyl chains was necessary to aid solubility. On mixing with N,N-bis(4-tert-butyphenyl)melamine in THF followed by slow evaporation, a viscous gel can form which is interpreted as evidence for the assembly of an infinite 2-D hydrogen bonded network.

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More information

Published date: 19 July 2004
Keywords: 2-amino-4, 6-bis-(4-tert-butylphenylamino)-1, 3, 5-triazine, cyanuric acid, hydrogen bonding, rosette motifmelamine, assemblies, polymers

Identifiers

Local EPrints ID: 20306
URI: http://eprints.soton.ac.uk/id/eprint/20306
ISSN: 0040-4020
PURE UUID: b2c3649a-a898-4c0d-85f2-7dd8930ce2ec

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Date deposited: 17 Feb 2006
Last modified: 15 Mar 2024 06:23

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Contributors

Author: M. J. Plater
Author: J. P. Sinclair
Author: S. Aiken
Author: T. Gelbrich

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