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Intramolecular C-H insertions adjacent to sulfur for the diastereoselective synthesis of thienofuranones

Intramolecular C-H insertions adjacent to sulfur for the diastereoselective synthesis of thienofuranones
Intramolecular C-H insertions adjacent to sulfur for the diastereoselective synthesis of thienofuranones
A new approach to the diastereoselective synthesis of thienofuranones is described in which an intramolecular 1,5-carbenoid C-H insertion adjacent to sulfur features as a key step.
metal carbene transformations, stereoselective-synthesis, organic-synthesis, cyclization, endo, exo-furofuranones
1359-7345
1772-1773
Skerry, Paul S.
c7ebeb7a-af57-4926-9ef6-6ff689c7077c
Swain, Nigel A.
522cad04-7679-4f30-9b4a-c4351017edad
Harrowven, David C.
bddcfab6-dbde-49df-aec2-42abbcf5d10b
Smyth, Donald
f043ce2f-8793-4993-93ee-56545d7d06ff
Bruton, Gordon
aa387dc2-6884-402c-809a-5abf66ec4247
Brown, Richard C.D.
21ce697a-7c3a-480e-919f-429a3d8550f5
Skerry, Paul S.
c7ebeb7a-af57-4926-9ef6-6ff689c7077c
Swain, Nigel A.
522cad04-7679-4f30-9b4a-c4351017edad
Harrowven, David C.
bddcfab6-dbde-49df-aec2-42abbcf5d10b
Smyth, Donald
f043ce2f-8793-4993-93ee-56545d7d06ff
Bruton, Gordon
aa387dc2-6884-402c-809a-5abf66ec4247
Brown, Richard C.D.
21ce697a-7c3a-480e-919f-429a3d8550f5

Skerry, Paul S., Swain, Nigel A., Harrowven, David C., Smyth, Donald, Bruton, Gordon and Brown, Richard C.D. (2004) Intramolecular C-H insertions adjacent to sulfur for the diastereoselective synthesis of thienofuranones. Chemical Communications, (15), 1772-1773. (doi:10.1039/b402603a).

Record type: Article

Abstract

A new approach to the diastereoselective synthesis of thienofuranones is described in which an intramolecular 1,5-carbenoid C-H insertion adjacent to sulfur features as a key step.

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More information

Published date: 2004
Additional Information: ChemComm
Related URLs:
Keywords: metal carbene transformations, stereoselective-synthesis, organic-synthesis, cyclization, endo, exo-furofuranones
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Identifiers

Local EPrints ID: 20321
URI: http://eprints.soton.ac.uk/id/eprint/20321
DOI: doi:10.1039/b402603a
ISSN: 1359-7345
PURE UUID: b9bbf92b-6125-407a-a599-80982909f86d
ORCID for David C. Harrowven: ORCID iD orcid.org/0000-0001-6730-3573
ORCID for Richard C.D. Brown: ORCID iD orcid.org/0000-0003-0156-7087

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Date deposited: 17 Feb 2006
Last modified: 16 Mar 2024 02:54

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Contributors

Author: Paul S. Skerry
Author: Nigel A. Swain
Author: David C. Harrowven ORCID iD
Author: Donald Smyth
Author: Gordon Bruton
Author: Richard C.D. Brown ORCID iD

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