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Riverine behaviour of uranium and lithium isotopes in an actively glaciated basaltic terrain

Pogge von Strandmann, Philip A.E., Burton, Kevin W., James, Rachael H., van Calsteren, Peter, Gíslason, Sigurður R. and Mokadem, Fatima (2006) Riverine behaviour of uranium and lithium isotopes in an actively glaciated basaltic terrain Earth and Planetary Science Letters, 251, (1-2), pp. 134-147. (doi:10.1016/j.epsl.2006.09.001).

Record type: Article


This study presents U and Li isotope and major and trace element data for the dissolved load, suspended particulates and bedload for Icelandic rivers draining predominantly basaltic catchments. Physical erosion rates range from 920 to 2084 t/km2/yr, with the higher values associated with glacier-fed rivers. Chemical erosion rates range from 45 to 91 t/km2/yr, with lower rates being associated with glacier-fed rivers. Uranium activity ratios, (234U/238U), are close to secular equilibrium in the suspended and bedloads, but all dissolved load samples show values greater than unity, ranging from 1.13 to 2.41. The highest (234U/238U) values are found in glacier-fed rivers, and can be attributed to ?-recoil effects, as grinding by glaciers locally enhances rates of physical weathering. Activity ratios in glacial rivers decrease with distance from the glacial source due to input from non-glacial tributaries which have high levels of dissolved uranium and lower activity ratios. In contrast, in non-glacial rivers, uranium activity ratios increase with distance downstream due to continued weathering in soils and of bedrock. The ?7Li value of the suspended load is always lower than that of the bedload due to preferential retention of 6Li in secondary minerals during weathering. In turn, the ?7Li value of the dissolved load is always greater than that of the bedload, ranging from 17.0 to 43.7‰. ?7Li for the dissolved load decreases with increasing levels of dissolved silicon, and the saturation index of secondary minerals, which suggests that ?7Li decreases with increasing chemical weathering. There is no correlation between ?7Li values and uranium activity ratios for the dissolved load for non-glacial rivers, but for glacier-fed rivers there is an increase in ?7Li with increasing (234U/238U), suggesting that where physical comminution of mineral grains by glaciers is high, chemical weathering is suppressed, and vice-versa.

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Published date: 15 November 2006
Keywords: uranium isotopes, lithium isotopes, basalt weathering, glacial weathering, iceland
Organisations: Marine Geoscience


Local EPrints ID: 206117
ISSN: 0012-821X
PURE UUID: 21701c08-f7b8-4f97-88e8-8b5dbdf00c86

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Date deposited: 14 Dec 2011 09:35
Last modified: 18 Jul 2017 11:03

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Author: Philip A.E. Pogge von Strandmann
Author: Kevin W. Burton
Author: Peter van Calsteren
Author: Sigurður R. Gíslason
Author: Fatima Mokadem

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