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The Crystal Structure of 4,6-Di-O-Benzyl-2,3-Dideoxy-2,2,3,3-Tetrafluorogalactose

The Crystal Structure of 4,6-Di-O-Benzyl-2,3-Dideoxy-2,2,3,3-Tetrafluorogalactose
The Crystal Structure of 4,6-Di-O-Benzyl-2,3-Dideoxy-2,2,3,3-Tetrafluorogalactose
The crystal structure of a reducing dibenzylated tetrafluorinated galactose derivative is reported. The compound crystallized as the ?-anomer, and a single OH···O hydrogen bond dominates the crystal packing, leading to a helical arrangement containing two galactose derivatives per turn. Interestingly, the helices are cross-linked by ArC–H···F contacts, but without significant Ar–Ar interactions.
0732-8303
618-625
Linclau, Bruno
19b9cacd-b8e8-4c65-af36-6352cade84ba
Golten, Samuel
214a0aed-950c-41b0-8b3f-b71614ce9d5e
Light, Mark
cf57314e-6856-491b-a8d2-2dffc452e161
Linclau, Bruno
19b9cacd-b8e8-4c65-af36-6352cade84ba
Golten, Samuel
214a0aed-950c-41b0-8b3f-b71614ce9d5e
Light, Mark
cf57314e-6856-491b-a8d2-2dffc452e161

Linclau, Bruno, Golten, Samuel and Light, Mark (2011) The Crystal Structure of 4,6-Di-O-Benzyl-2,3-Dideoxy-2,2,3,3-Tetrafluorogalactose. [in special issue: European Young Investigator Workshop. “Carbohydrate Chemistry: From Synthesis to Applications,” Lyon, France, 2011] Journal of Carbohydrate Chemistry, 30 (7-9), 618-625. (doi:10.1080/07328303.2011.618895).

Record type: Article

Abstract

The crystal structure of a reducing dibenzylated tetrafluorinated galactose derivative is reported. The compound crystallized as the ?-anomer, and a single OH···O hydrogen bond dominates the crystal packing, leading to a helical arrangement containing two galactose derivatives per turn. Interestingly, the helices are cross-linked by ArC–H···F contacts, but without significant Ar–Ar interactions.

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e-pub ahead of print date: 14 December 2011
Published date: 2011
Organisations: Chemistry

Identifiers

Local EPrints ID: 206301
URI: http://eprints.soton.ac.uk/id/eprint/206301
ISSN: 0732-8303
PURE UUID: 3d8109a5-db85-4ea0-a116-26580e8c9fdf
ORCID for Bruno Linclau: ORCID iD orcid.org/0000-0001-8762-0170
ORCID for Mark Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 19 Dec 2011 10:34
Last modified: 18 Feb 2021 16:55

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