Non-biaryl atropisomers derived from carbohydrates. Part 4: Absolute stereochemistry of carbohydrate-based imidazolidine-2-ones and 2-thiones with axial and central chirality
Non-biaryl atropisomers derived from carbohydrates. Part 4: Absolute stereochemistry of carbohydrate-based imidazolidine-2-ones and 2-thiones with axial and central chirality
NMR spectroscopy has proven to be an enabling methodology in elucidating the axial chirality of a series of non-biaryl atropisomers attached to a carbohydrate moiety, based on deshielding effects caused by the aromatic ring.
atropisomerism, carbohydrates, imidazolidines, molecular mechanics, nmr spectroscopy, derivatives, isocyanates
7945-7959
Ávalos, Martín
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Babiano, Reyes
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Cintas, Pedro
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Hursthouse, Michael B.
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Jiménez, José L.
074cc8fd-9ea1-41fc-b8b6-551d26e5fcd3
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Palacios, Juan C.
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Silvero, Guadalupe
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15 August 2005
Ávalos, Martín
2d0b39c7-15a3-4f90-bdfb-8e4b6e69c64a
Babiano, Reyes
b7ffd91c-bacd-4372-ab99-fc30ac2450ae
Cintas, Pedro
29979233-8382-47a8-bde7-1faf4869308c
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Jiménez, José L.
074cc8fd-9ea1-41fc-b8b6-551d26e5fcd3
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Palacios, Juan C.
2c06e379-89b3-46b1-95c8-7f5057732f9f
Silvero, Guadalupe
8e6975cc-88ec-4809-8040-bc84413d57d6
Ávalos, Martín, Babiano, Reyes, Cintas, Pedro, Hursthouse, Michael B., Jiménez, José L., Light, Mark E., Palacios, Juan C. and Silvero, Guadalupe
(2005)
Non-biaryl atropisomers derived from carbohydrates. Part 4: Absolute stereochemistry of carbohydrate-based imidazolidine-2-ones and 2-thiones with axial and central chirality.
Tetrahedron, 61 (33), .
(doi:10.1016/j.tet.2005.06.018).
Abstract
NMR spectroscopy has proven to be an enabling methodology in elucidating the axial chirality of a series of non-biaryl atropisomers attached to a carbohydrate moiety, based on deshielding effects caused by the aromatic ring.
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Published date: 15 August 2005
Keywords:
atropisomerism, carbohydrates, imidazolidines, molecular mechanics, nmr spectroscopy, derivatives, isocyanates
Identifiers
Local EPrints ID: 20706
URI: http://eprints.soton.ac.uk/id/eprint/20706
ISSN: 0040-4020
PURE UUID: 2e1d70c1-a6e1-4be7-acbc-53e29dc796e5
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Date deposited: 28 Feb 2006
Last modified: 16 Mar 2024 03:04
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Contributors
Author:
Martín Ávalos
Author:
Reyes Babiano
Author:
Pedro Cintas
Author:
José L. Jiménez
Author:
Juan C. Palacios
Author:
Guadalupe Silvero
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