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N-Heterocyclic carbene adducts of orthopalladated triarylphosphite complexes

N-Heterocyclic carbene adducts of orthopalladated triarylphosphite complexes
N-Heterocyclic carbene adducts of orthopalladated triarylphosphite complexes
Carbene adducts of orthopalladated triarylphosphite complexes have been synthesised and characterised. The structures of three of these complexes were determined by single-crystal X-ray analysis. The complexes are active in the Suzuki coupling of a range of aryl bromide substrates.
high-activity catalysts, aryl chlorides, coupling reactions, phosphite complexes, aromatic chlorides, suzuki, chloroarenes, reactivity, amination
0300-9246
2774-2779
Bedford, Robin B.
42532c45-cb80-48cd-9e93-8c2d5059eabe
Betham, Michael
0cd66656-1b0f-40b4-8dc7-a7b3121257f6
Blake, Michael E.
07856b0a-5a28-48a9-96f5-5f09bdbd7f9f
Frost, Robert M.
fcce38bd-c584-443d-a6eb-bda4c97d5ee3
Horton, Peter N.
48f162d1-d6ce-43c1-aeef-d58b3ec702b8
Hursthouse, Michael B.
a65b4d35-2ea0-47e7-938a-d744f4d9ba28
López-Nicolás, Rosa-María
f8a4bb4c-75c6-4311-97a2-33bf60737cb4
Bedford, Robin B.
42532c45-cb80-48cd-9e93-8c2d5059eabe
Betham, Michael
0cd66656-1b0f-40b4-8dc7-a7b3121257f6
Blake, Michael E.
07856b0a-5a28-48a9-96f5-5f09bdbd7f9f
Frost, Robert M.
fcce38bd-c584-443d-a6eb-bda4c97d5ee3
Horton, Peter N.
48f162d1-d6ce-43c1-aeef-d58b3ec702b8
Hursthouse, Michael B.
a65b4d35-2ea0-47e7-938a-d744f4d9ba28
López-Nicolás, Rosa-María
f8a4bb4c-75c6-4311-97a2-33bf60737cb4

Bedford, Robin B., Betham, Michael, Blake, Michael E., Frost, Robert M., Horton, Peter N., Hursthouse, Michael B. and López-Nicolás, Rosa-María (2005) N-Heterocyclic carbene adducts of orthopalladated triarylphosphite complexes. Dalton Transactions, (16), 2774-2779.

Record type: Article

Abstract

Carbene adducts of orthopalladated triarylphosphite complexes have been synthesised and characterised. The structures of three of these complexes were determined by single-crystal X-ray analysis. The complexes are active in the Suzuki coupling of a range of aryl bromide substrates.

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More information

Published date: 2005
Keywords: high-activity catalysts, aryl chlorides, coupling reactions, phosphite complexes, aromatic chlorides, suzuki, chloroarenes, reactivity, amination

Identifiers

Local EPrints ID: 20717
URI: https://eprints.soton.ac.uk/id/eprint/20717
ISSN: 0300-9246
PURE UUID: 6e4c29bc-25aa-409d-833e-41aeb02d324c

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Date deposited: 01 Mar 2006
Last modified: 17 Oct 2017 11:34

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Contributors

Author: Robin B. Bedford
Author: Michael Betham
Author: Michael E. Blake
Author: Robert M. Frost
Author: Peter N. Horton
Author: Michael B. Hursthouse
Author: Rosa-María López-Nicolás

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