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Synthesis of an alkene functionalised thiamacrocycle, 2,11-divinyl-1,4,7,10,13,16-hexathiacyclooctadeca-2,11-diene

Synthesis of an alkene functionalised thiamacrocycle, 2,11-divinyl-1,4,7,10,13,16-hexathiacyclooctadeca-2,11-diene
Synthesis of an alkene functionalised thiamacrocycle, 2,11-divinyl-1,4,7,10,13,16-hexathiacyclooctadeca-2,11-diene
Base-catalysed rearrangement of 1,4,7-trithiacycloundec-9-yne affords 2,11-Divinyl-1,4,7,10,13,16-hexathiacyclooctadeca-2,11-diene characterised by NMR spectroscopy and X-ray crystallography. The 18-membered macrocycle has six of the 12 C–S bonds in gauche configurations.
thioether, macrocycle, alkene, crown-thioether, complexes, chemistry
488-490
Berko, Aaron
1fe532b0-bf10-430d-9193-60f06580ca2c
Horton, Peter N.
48f162d1-d6ce-43c1-aeef-d58b3ec702b8
Hursthouse, Michael B.
a65b4d35-2ea0-47e7-938a-d744f4d9ba28
Packer, Robert J.
5a741037-4709-49a3-9f77-90de5765d6ad
Went, Michael J.
0427c40d-2ae5-4ed2-8443-c5639a35187b
Berko, Aaron
1fe532b0-bf10-430d-9193-60f06580ca2c
Horton, Peter N.
48f162d1-d6ce-43c1-aeef-d58b3ec702b8
Hursthouse, Michael B.
a65b4d35-2ea0-47e7-938a-d744f4d9ba28
Packer, Robert J.
5a741037-4709-49a3-9f77-90de5765d6ad
Went, Michael J.
0427c40d-2ae5-4ed2-8443-c5639a35187b

Berko, Aaron, Horton, Peter N., Hursthouse, Michael B., Packer, Robert J. and Went, Michael J. (2005) Synthesis of an alkene functionalised thiamacrocycle, 2,11-divinyl-1,4,7,10,13,16-hexathiacyclooctadeca-2,11-diene. Inorganic Chemistry Communications, 8 (5), 488-490. (doi:10.1016/j.inoche.2005.03.003).

Record type: Article

Abstract

Base-catalysed rearrangement of 1,4,7-trithiacycloundec-9-yne affords 2,11-Divinyl-1,4,7,10,13,16-hexathiacyclooctadeca-2,11-diene characterised by NMR spectroscopy and X-ray crystallography. The 18-membered macrocycle has six of the 12 C–S bonds in gauche configurations.

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More information

Published date: 2005
Keywords: thioether, macrocycle, alkene, crown-thioether, complexes, chemistry

Identifiers

Local EPrints ID: 20723
URI: https://eprints.soton.ac.uk/id/eprint/20723
PURE UUID: cc477bc0-4d40-43ce-b602-445c64a624ca

Catalogue record

Date deposited: 01 Mar 2006
Last modified: 17 Jul 2017 16:28

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