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Group 4 salicyloxazolines are potent polymerization catalysts

Group 4 salicyloxazolines are potent polymerization catalysts
Group 4 salicyloxazolines are potent polymerization catalysts
Octahedral titanium and zirconium complexes based on salicyloxazoline ligands with sterically demanding ortho-substituents provide a new family of extremely active ethene polymerization catalysts [up to 10(8) g PE (mol bar h)–1] which are in some cases "single site".
imine chelate ligands, olefin polymerization, zirconium complexes, ethylene polymerization, fi catalysts, mono(salicylaldiminato)titanium, delta-2-thiazolines, delta-2-oxazolines, family
0300-9246
3611-3613
Bott, Robyn K.J.
2fb7cba1-fc74-4aeb-96f7-c9f59e6af9e2
Hammond, Max
2d716aee-60fe-41e9-a3c3-49cf07028e26
Horton, Peter N.
48f162d1-d6ce-43c1-aeef-d58b3ec702b8
Lancaster, Simon J.
06d860ba-99d7-4be1-a78d-39505c0fc14b
Bochmann, Manfred
ec2bb201-23cc-4f91-aa80-258e6c8cc9fb
Scott, Peter
3a25962b-85f6-4bec-a588-11bbdd4ec148
Bott, Robyn K.J.
2fb7cba1-fc74-4aeb-96f7-c9f59e6af9e2
Hammond, Max
2d716aee-60fe-41e9-a3c3-49cf07028e26
Horton, Peter N.
48f162d1-d6ce-43c1-aeef-d58b3ec702b8
Lancaster, Simon J.
06d860ba-99d7-4be1-a78d-39505c0fc14b
Bochmann, Manfred
ec2bb201-23cc-4f91-aa80-258e6c8cc9fb
Scott, Peter
3a25962b-85f6-4bec-a588-11bbdd4ec148

Bott, Robyn K.J., Hammond, Max, Horton, Peter N., Lancaster, Simon J., Bochmann, Manfred and Scott, Peter (2005) Group 4 salicyloxazolines are potent polymerization catalysts. Dalton Transactions, (22), 3611-3613.

Record type: Article

Abstract

Octahedral titanium and zirconium complexes based on salicyloxazoline ligands with sterically demanding ortho-substituents provide a new family of extremely active ethene polymerization catalysts [up to 10(8) g PE (mol bar h)–1] which are in some cases "single site".

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More information

Published date: 21 November 2005
Keywords: imine chelate ligands, olefin polymerization, zirconium complexes, ethylene polymerization, fi catalysts, mono(salicylaldiminato)titanium, delta-2-thiazolines, delta-2-oxazolines, family

Identifiers

Local EPrints ID: 20730
URI: https://eprints.soton.ac.uk/id/eprint/20730
ISSN: 0300-9246
PURE UUID: 8b9dfb87-0a6e-4000-8c48-11565e2222c6

Catalogue record

Date deposited: 01 Mar 2006
Last modified: 12 Oct 2017 14:39

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