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ortho-Phenylenediamine bis-urea–carboxylate: a new reliable supramolecular synthon

ortho-Phenylenediamine bis-urea–carboxylate: a new reliable supramolecular synthon
ortho-Phenylenediamine bis-urea–carboxylate: a new reliable supramolecular synthon
The reliability of the mode of carboxylate binding to ortho-phenylenediamine based bis-urea clefts is demonstrated in a variety of systems including a hydrogen bonded tape suggesting that this DDDD-AA supramolecular synthon may find application in crystal engineered systems in the future.
triple-helical array, solid-state, molecular approach, anion control, recognition, polymer, dimers
1466-8033
586-591
Brooks, Simon J.
fcf66c9a-5e4d-47cf-bc9f-e7c8886a061a
Gale, Philip A.
ce0aa62f-d081-408b-8b00-6d954058afab
Light, Mark E.
13b5eb33-3114-4fb7-8500-90ce69e9933c
Brooks, Simon J.
fcf66c9a-5e4d-47cf-bc9f-e7c8886a061a
Gale, Philip A.
ce0aa62f-d081-408b-8b00-6d954058afab
Light, Mark E.
13b5eb33-3114-4fb7-8500-90ce69e9933c

Brooks, Simon J., Gale, Philip A. and Light, Mark E. (2005) ortho-Phenylenediamine bis-urea–carboxylate: a new reliable supramolecular synthon. CrystEngComm, 7, 586-591. (doi:10.1039/b511932d).

Record type: Article

Abstract

The reliability of the mode of carboxylate binding to ortho-phenylenediamine based bis-urea clefts is demonstrated in a variety of systems including a hydrogen bonded tape suggesting that this DDDD-AA supramolecular synthon may find application in crystal engineered systems in the future.

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More information

Published date: 14 October 2005
Keywords: triple-helical array, solid-state, molecular approach, anion control, recognition, polymer, dimers
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Identifiers

Local EPrints ID: 20739
URI: http://eprints.soton.ac.uk/id/eprint/20739
DOI: doi:10.1039/b511932d
ISSN: 1466-8033
PURE UUID: 67ef85c0-a8b8-42a6-8100-dd5219d48f6b

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Date deposited: 02 Mar 2006
Last modified: 15 Mar 2024 06:25

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Contributors

Author: Simon J. Brooks
Author: Philip A. Gale
Author: Mark E. Light

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