Carboxylate complexation by 1,1'-(1,2-phenylene)bis(3-phenylurea) in solution and the solid state
Carboxylate complexation by 1,1'-(1,2-phenylene)bis(3-phenylurea) in solution and the solid state
A simple bis-urea containing anion receptor, synthesised from ortho-phenylenediamine, has been shown to have excellent selectivity for carboxylates in solution, with a crystal structure elucidation of the benzoate complex showing four hydrogen bonds between the receptor and anion in the solid state.
anion receptors, molecular recognition, binding-sites, urea, solvents
4696-4698
Brooks, Simon J.
fcf66c9a-5e4d-47cf-bc9f-e7c8886a061a
Gale, Philip A.
ce0aa62f-d081-408b-8b00-6d954058afab
Light, Mark E.
13b5eb33-3114-4fb7-8500-90ce69e9933c
2005
Brooks, Simon J.
fcf66c9a-5e4d-47cf-bc9f-e7c8886a061a
Gale, Philip A.
ce0aa62f-d081-408b-8b00-6d954058afab
Light, Mark E.
13b5eb33-3114-4fb7-8500-90ce69e9933c
Brooks, Simon J., Gale, Philip A. and Light, Mark E.
(2005)
Carboxylate complexation by 1,1'-(1,2-phenylene)bis(3-phenylurea) in solution and the solid state.
Chemical Communications, (37), .
(doi:10.1039/b508144k).
Abstract
A simple bis-urea containing anion receptor, synthesised from ortho-phenylenediamine, has been shown to have excellent selectivity for carboxylates in solution, with a crystal structure elucidation of the benzoate complex showing four hydrogen bonds between the receptor and anion in the solid state.
This record has no associated files available for download.
More information
Published date: 2005
Keywords:
anion receptors, molecular recognition, binding-sites, urea, solvents
Identifiers
Local EPrints ID: 20740
URI: http://eprints.soton.ac.uk/id/eprint/20740
ISSN: 1359-7345
PURE UUID: 532f2b0c-856a-415c-a8d3-de5a90f0ace2
Catalogue record
Date deposited: 02 Mar 2006
Last modified: 15 Mar 2024 06:25
Export record
Altmetrics
Contributors
Author:
Simon J. Brooks
Author:
Philip A. Gale
Author:
Mark E. Light
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics