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Carboxylate complexation by 1,1'-(1,2-phenylene)bis(3-phenylurea) in solution and the solid state

Carboxylate complexation by 1,1'-(1,2-phenylene)bis(3-phenylurea) in solution and the solid state
Carboxylate complexation by 1,1'-(1,2-phenylene)bis(3-phenylurea) in solution and the solid state
A simple bis-urea containing anion receptor, synthesised from ortho-phenylenediamine, has been shown to have excellent selectivity for carboxylates in solution, with a crystal structure elucidation of the benzoate complex showing four hydrogen bonds between the receptor and anion in the solid state.
anion receptors, molecular recognition, binding-sites, urea, solvents
1359-7345
4696-4698
Brooks, Simon J.
fcf66c9a-5e4d-47cf-bc9f-e7c8886a061a
Gale, Philip A.
ce0aa62f-d081-408b-8b00-6d954058afab
Light, Mark E.
13b5eb33-3114-4fb7-8500-90ce69e9933c
Brooks, Simon J.
fcf66c9a-5e4d-47cf-bc9f-e7c8886a061a
Gale, Philip A.
ce0aa62f-d081-408b-8b00-6d954058afab
Light, Mark E.
13b5eb33-3114-4fb7-8500-90ce69e9933c

Brooks, Simon J., Gale, Philip A. and Light, Mark E. (2005) Carboxylate complexation by 1,1'-(1,2-phenylene)bis(3-phenylurea) in solution and the solid state. Chemical Communications, (37), 4696-4698. (doi:10.1039/b508144k).

Record type: Article

Abstract

A simple bis-urea containing anion receptor, synthesised from ortho-phenylenediamine, has been shown to have excellent selectivity for carboxylates in solution, with a crystal structure elucidation of the benzoate complex showing four hydrogen bonds between the receptor and anion in the solid state.

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More information

Published date: 2005
Keywords: anion receptors, molecular recognition, binding-sites, urea, solvents

Identifiers

Local EPrints ID: 20740
URI: http://eprints.soton.ac.uk/id/eprint/20740
ISSN: 1359-7345
PURE UUID: 532f2b0c-856a-415c-a8d3-de5a90f0ace2

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Date deposited: 02 Mar 2006
Last modified: 15 Jul 2019 19:25

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Contributors

Author: Simon J. Brooks
Author: Philip A. Gale
Author: Mark E. Light

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