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trans-4-[(4-Dimethylaminophenyl)ethenyl]-N-methylquinolinium p-toluenesulfonate monohydrate

trans-4-[(4-Dimethylaminophenyl)ethenyl]-N-methylquinolinium p-toluenesulfonate monohydrate
trans-4-[(4-Dimethylaminophenyl)ethenyl]-N-methylquinolinium p-toluenesulfonate monohydrate
In the title salt, C20H21N2+ · C7H7SO3- · H2O, the quinolinium cation exhibits a large molecular non- linear optical ( NLO) response, as determined by Stark spectroscopy, but crystallization in the centrosymmetric space group P (1) over bar precludes significant bulk NLO effects. Intermolecular O - H ... O and weak C - H ... O hydrogen bonding links the constituent molecules into a three- dimensional network.
2nd-order optical nonlinearities, organic-crystal, tosylate dast, wave-guides, salts, growth, dyes, hyperpolarizabilities, fabrication
o464-o467
Coe, B.J.
bcf93592-85df-4a69-a1cf-aea0a9152789
Hall, J.J.
32a2a268-de75-4f88-8dac-f9a7dca83230
Harris, J.A.
1c5b576b-d42f-4099-b9c8-9df833b9366c
Brunschwig, B.S.
9a299f7b-be4d-4b06-8a45-3b9066f1a3b0
Coles, S.J.
312b6dc7-a929-462c-b4ef-c9af32fcedc1
Hursthouse, M.B.
427032bc-428c-4396-adb0-b38e87e908e7
Coe, B.J.
bcf93592-85df-4a69-a1cf-aea0a9152789
Hall, J.J.
32a2a268-de75-4f88-8dac-f9a7dca83230
Harris, J.A.
1c5b576b-d42f-4099-b9c8-9df833b9366c
Brunschwig, B.S.
9a299f7b-be4d-4b06-8a45-3b9066f1a3b0
Coles, S.J.
312b6dc7-a929-462c-b4ef-c9af32fcedc1
Hursthouse, M.B.
427032bc-428c-4396-adb0-b38e87e908e7

Coe, B.J., Hall, J.J., Harris, J.A., Brunschwig, B.S., Coles, S.J. and Hursthouse, M.B. (2005) trans-4-[(4-Dimethylaminophenyl)ethenyl]-N-methylquinolinium p-toluenesulfonate monohydrate. Acta Crystallographica Section E Crystallographic Communications, 61 (2), o464-o467. (doi:10.1107/S1600536805002138).

Record type: Article

Abstract

In the title salt, C20H21N2+ · C7H7SO3- · H2O, the quinolinium cation exhibits a large molecular non- linear optical ( NLO) response, as determined by Stark spectroscopy, but crystallization in the centrosymmetric space group P (1) over bar precludes significant bulk NLO effects. Intermolecular O - H ... O and weak C - H ... O hydrogen bonding links the constituent molecules into a three- dimensional network.

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More information

Published date: 2005
Keywords: 2nd-order optical nonlinearities, organic-crystal, tosylate dast, wave-guides, salts, growth, dyes, hyperpolarizabilities, fabrication

Identifiers

Local EPrints ID: 20758
URI: http://eprints.soton.ac.uk/id/eprint/20758
PURE UUID: 310afae5-91ae-4a5a-8e2f-da4bba6b885e

Catalogue record

Date deposited: 02 Mar 2006
Last modified: 15 Jul 2019 19:25

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