Structural investigation of the bridged activated complex in the reaction between hexachloroiridate(IV) and pentacyanocobaltate(II)
Structural investigation of the bridged activated complex in the reaction between hexachloroiridate(IV) and pentacyanocobaltate(II)
Time resolved energy dispersive X-ray absorption spectroscopy has been used to follow the structural evolution of the inner-sphere electron transfer reaction between [IrCl6]2– and [Co(CN)5]3–, and to characterise the local structure of the iridium metal centre in the bridged activated complex formed during the reaction.
3814-3817
Diaz-Moreno, Sofia
4e280df3-7f62-4280-8058-2803c740ae00
Bowron, Daniel T.
5298ea68-9e1f-4d5d-9183-da8b260f024a
Evans, John
05890433-0155-49fe-a65d-38c90ea25c69
7 December 2005
Diaz-Moreno, Sofia
4e280df3-7f62-4280-8058-2803c740ae00
Bowron, Daniel T.
5298ea68-9e1f-4d5d-9183-da8b260f024a
Evans, John
05890433-0155-49fe-a65d-38c90ea25c69
Diaz-Moreno, Sofia, Bowron, Daniel T. and Evans, John
(2005)
Structural investigation of the bridged activated complex in the reaction between hexachloroiridate(IV) and pentacyanocobaltate(II).
Dalton Transactions, (23), .
(doi:10.1039/b507738a).
Abstract
Time resolved energy dispersive X-ray absorption spectroscopy has been used to follow the structural evolution of the inner-sphere electron transfer reaction between [IrCl6]2– and [Co(CN)5]3–, and to characterise the local structure of the iridium metal centre in the bridged activated complex formed during the reaction.
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Published date: 7 December 2005
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Local EPrints ID: 20780
URI: http://eprints.soton.ac.uk/id/eprint/20780
ISSN: 1477-9226
PURE UUID: fd0ae077-d024-4e33-8bdc-7a7ca7464154
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Date deposited: 03 Mar 2006
Last modified: 29 Oct 2024 02:32
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Author:
Sofia Diaz-Moreno
Author:
Daniel T. Bowron
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