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Structural investigation of the bridged activated complex in the reaction between hexachloroiridate(IV) and pentacyanocobaltate(II)

Structural investigation of the bridged activated complex in the reaction between hexachloroiridate(IV) and pentacyanocobaltate(II)
Structural investigation of the bridged activated complex in the reaction between hexachloroiridate(IV) and pentacyanocobaltate(II)
Time resolved energy dispersive X-ray absorption spectroscopy has been used to follow the structural evolution of the inner-sphere electron transfer reaction between [IrCl6]2– and [Co(CN)5]3–, and to characterise the local structure of the iridium metal centre in the bridged activated complex formed during the reaction.
1477-9226
3814-3817
Diaz-Moreno, Sofia
4e280df3-7f62-4280-8058-2803c740ae00
Bowron, Daniel T.
5298ea68-9e1f-4d5d-9183-da8b260f024a
Evans, John
05890433-0155-49fe-a65d-38c90ea25c69
Diaz-Moreno, Sofia
4e280df3-7f62-4280-8058-2803c740ae00
Bowron, Daniel T.
5298ea68-9e1f-4d5d-9183-da8b260f024a
Evans, John
05890433-0155-49fe-a65d-38c90ea25c69

Diaz-Moreno, Sofia, Bowron, Daniel T. and Evans, John (2005) Structural investigation of the bridged activated complex in the reaction between hexachloroiridate(IV) and pentacyanocobaltate(II). Dalton Transactions, (23), 3814-3817. (doi:10.1039/b507738a).

Record type: Article

Abstract

Time resolved energy dispersive X-ray absorption spectroscopy has been used to follow the structural evolution of the inner-sphere electron transfer reaction between [IrCl6]2– and [Co(CN)5]3–, and to characterise the local structure of the iridium metal centre in the bridged activated complex formed during the reaction.

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Published date: 7 December 2005

Identifiers

Local EPrints ID: 20780
URI: http://eprints.soton.ac.uk/id/eprint/20780
ISSN: 1477-9226
PURE UUID: fd0ae077-d024-4e33-8bdc-7a7ca7464154

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Date deposited: 03 Mar 2006
Last modified: 15 Jul 2019 19:25

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Contributors

Author: Sofia Diaz-Moreno
Author: Daniel T. Bowron
Author: John Evans

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