Structural investigation of the bridged activated complex in the reaction between hexachloroiridate(IV) and pentacyanocobaltate(II)
Structural investigation of the bridged activated complex in the reaction between hexachloroiridate(IV) and pentacyanocobaltate(II)
Time resolved energy dispersive X-ray absorption spectroscopy has been used to follow the structural evolution of the inner-sphere electron transfer reaction between [IrCl6]2– and [Co(CN)5]3–, and to characterise the local structure of the iridium metal centre in the bridged activated complex formed during the reaction.
3814-3817
Diaz-Moreno, Sofia
4e280df3-7f62-4280-8058-2803c740ae00
Bowron, Daniel T.
5298ea68-9e1f-4d5d-9183-da8b260f024a
Evans, John
05890433-0155-49fe-a65d-38c90ea25c69
7 December 2005
Diaz-Moreno, Sofia
4e280df3-7f62-4280-8058-2803c740ae00
Bowron, Daniel T.
5298ea68-9e1f-4d5d-9183-da8b260f024a
Evans, John
05890433-0155-49fe-a65d-38c90ea25c69
Diaz-Moreno, Sofia, Bowron, Daniel T. and Evans, John
(2005)
Structural investigation of the bridged activated complex in the reaction between hexachloroiridate(IV) and pentacyanocobaltate(II).
Dalton Transactions, (23), .
(doi:10.1039/b507738a).
Abstract
Time resolved energy dispersive X-ray absorption spectroscopy has been used to follow the structural evolution of the inner-sphere electron transfer reaction between [IrCl6]2– and [Co(CN)5]3–, and to characterise the local structure of the iridium metal centre in the bridged activated complex formed during the reaction.
This record has no associated files available for download.
More information
Published date: 7 December 2005
Identifiers
Local EPrints ID: 20780
URI: http://eprints.soton.ac.uk/id/eprint/20780
ISSN: 1477-9226
PURE UUID: fd0ae077-d024-4e33-8bdc-7a7ca7464154
Catalogue record
Date deposited: 03 Mar 2006
Last modified: 15 Mar 2024 06:25
Export record
Altmetrics
Contributors
Author:
Sofia Diaz-Moreno
Author:
Daniel T. Bowron
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics