Birefringent cadmium-telluride-based metamaterial
Birefringent cadmium-telluride-based metamaterial
 
  A CdTe-based optical metamaterial, with large induced optical birefringence (4%), has been produced and its optical properties fully characterized and modeled over the spectral range 1500- 450 nm. This metamaterial, which is related to mesoporous silica, is made using electrochemical deposition in the presence of a lyotropic liquid crystal template. This process produces a stoichiometric CdTe film containing a hexagonal array of similar to4.2 nm cylindrical pores with interpore separation similar to6.5 nm. A model of the dielectric properties of the films indicates that their birefringence can be entirely attributed to the film's nanoporosity.
  liquid-crystalline phases, mesoporous silica, films, deposition, cdte
  
  
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      Markham, M.L.
      
        9a5b7792-d6ab-4d19-ae5a-19d6547e0249
      
     
  
    
      Baumberg, J.J.
      
        78e1ea7e-8c70-404c-bf84-59aafe75cd07
      
     
  
    
      Smith, D.C.
      
        d9b2c02d-b7ea-498b-9ea1-208a1681536f
      
     
  
    
      Li, X.
      
        ea8135d4-1bd7-4771-85cd-eb8f2a264654
      
     
  
    
      Gabriel, T.
      
        661423e0-f3f3-4130-9a65-d350e4cac79f
      
     
  
    
      Attard, G.S.
      
        3219075d-2364-4f00-aeb9-1d90f8cd0d36
      
     
  
    
      Nandhakumar, I.
      
        e9850fe5-1152-4df8-8a26-ed44b5564b04
      
     
  
  
   
  
  
    
      3 January 2005
    
    
  
  
    
      Markham, M.L.
      
        9a5b7792-d6ab-4d19-ae5a-19d6547e0249
      
     
  
    
      Baumberg, J.J.
      
        78e1ea7e-8c70-404c-bf84-59aafe75cd07
      
     
  
    
      Smith, D.C.
      
        d9b2c02d-b7ea-498b-9ea1-208a1681536f
      
     
  
    
      Li, X.
      
        ea8135d4-1bd7-4771-85cd-eb8f2a264654
      
     
  
    
      Gabriel, T.
      
        661423e0-f3f3-4130-9a65-d350e4cac79f
      
     
  
    
      Attard, G.S.
      
        3219075d-2364-4f00-aeb9-1d90f8cd0d36
      
     
  
    
      Nandhakumar, I.
      
        e9850fe5-1152-4df8-8a26-ed44b5564b04
      
     
  
       
    
 
  
    
      
  
  
  
  
  
  
    Markham, M.L., Baumberg, J.J., Smith, D.C., Li, X., Gabriel, T., Attard, G.S. and Nandhakumar, I.
  
  
  
  
   
    (2005)
  
  
    
    Birefringent cadmium-telluride-based metamaterial.
  
  
  
  
    Applied Physics Letters, 86 (1), .
  
   (doi:10.1063/1.1844035). 
  
  
   
  
  
  
  
  
   
  
    
    
      
        
          Abstract
          A CdTe-based optical metamaterial, with large induced optical birefringence (4%), has been produced and its optical properties fully characterized and modeled over the spectral range 1500- 450 nm. This metamaterial, which is related to mesoporous silica, is made using electrochemical deposition in the presence of a lyotropic liquid crystal template. This process produces a stoichiometric CdTe film containing a hexagonal array of similar to4.2 nm cylindrical pores with interpore separation similar to6.5 nm. A model of the dielectric properties of the films indicates that their birefringence can be entirely attributed to the film's nanoporosity.
         
      
      
        
          
            
  
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      Published date: 3 January 2005
 
    
  
  
    
  
    
  
    
  
    
  
    
  
    
     
        Keywords:
        liquid-crystalline phases, mesoporous silica, films, deposition, cdte
      
    
  
    
  
    
  
  
        Identifiers
        Local EPrints ID: 20860
        URI: http://eprints.soton.ac.uk/id/eprint/20860
        
          
        
        
        
          ISSN: 0003-6951
        
        
          PURE UUID: 57084e60-d125-4496-a9a4-8f1cb7a82b49
        
  
    
        
          
        
    
        
          
        
    
        
          
            
          
        
    
        
          
            
          
        
    
        
          
        
    
        
          
            
              
            
          
        
    
        
          
            
              
            
          
        
    
  
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  Date deposited: 28 Feb 2006
  Last modified: 21 Aug 2025 01:43
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      Contributors
      
          
          Author:
          
            
            
              M.L. Markham
            
          
        
      
          
          Author:
          
            
            
              J.J. Baumberg
            
          
        
      
        
      
          
          Author:
          
            
              
              
                X. Li
              
              
            
            
          
        
      
          
          Author:
          
            
            
              T. Gabriel
            
          
        
      
        
      
        
      
      
      
    
  
   
  
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