The University of Southampton
×
Filter your search:
University of Southampton Institutional Repository

Zirconium and titanium amido complexes with 3,3-dimethyl-1,5-diaza-8-oxacyclodecane; facile C-H activation of the macrocyclic rim

Zirconium and titanium amido complexes with 3,3-dimethyl-1,5-diaza-8-oxacyclodecane; facile C-H activation of the macrocyclic rim
Zirconium and titanium amido complexes with 3,3-dimethyl-1,5-diaza-8-oxacyclodecane; facile C-H activation of the macrocyclic rim
Reaction of the dilithium salt of 3,3-dimethyl-1,5-diaza-8- oxacyclodecane, [(NLi)(2)O], with Zr(NEt)(2)Cl-2(thf)(2) gave the formally 20e(-) complex [Zr(N2O)(2)]; metallation of the macrocycle [(NH)(2)O], with Ti(benzyl)(4) gave rise to [(N2O)* Ti(benzyl)](2) in which the trianionic diamido (N2O)* was formed by an unprecedented C-H activation of the carbon a to the amido nitrogen.
metal complexes, main-group, ligands, chemistry, reagents
0300-9246
427-428
Porter, Robin M.
0f562df9-d217-4c62-a3c5-66b67262dcfb
Danopoulos, Andreas A.
4919c13e-ebe4-4456-b329-c806c8e22236
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Titcomb, Lisa R.
2fc9e8a3-118c-4b69-a343-45d6a12a51c5
Porter, Robin M.
0f562df9-d217-4c62-a3c5-66b67262dcfb
Danopoulos, Andreas A.
4919c13e-ebe4-4456-b329-c806c8e22236
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Titcomb, Lisa R.
2fc9e8a3-118c-4b69-a343-45d6a12a51c5

Porter, Robin M., Danopoulos, Andreas A., Reid, Gillian and Titcomb, Lisa R. (2005) Zirconium and titanium amido complexes with 3,3-dimethyl-1,5-diaza-8-oxacyclodecane; facile C-H activation of the macrocyclic rim. Dalton Transactions, (3), 427-428. (doi:10.1039/b418431a).

Record type: Article

Abstract

Reaction of the dilithium salt of 3,3-dimethyl-1,5-diaza-8- oxacyclodecane, [(NLi)(2)O], with Zr(NEt)(2)Cl-2(thf)(2) gave the formally 20e(-) complex [Zr(N2O)(2)]; metallation of the macrocycle [(NH)(2)O], with Ti(benzyl)(4) gave rise to [(N2O)* Ti(benzyl)](2) in which the trianionic diamido (N2O)* was formed by an unprecedented C-H activation of the carbon a to the amido nitrogen.

This record has no associated files available for download.

More information

Published date: 2005
Keywords: metal complexes, main-group, ligands, chemistry, reagents
Learn more about Chemistry research

Identifiers

Local EPrints ID: 20890
URI: http://eprints.soton.ac.uk/id/eprint/20890
DOI: doi:10.1039/b418431a
ISSN: 0300-9246
PURE UUID: 288b3af8-0ce9-4cef-8d21-53fc67af4c7d
ORCID for Gillian Reid: ORCID iD orcid.org/0000-0001-5349-3468

Catalogue record

Date deposited: 02 Mar 2006
Last modified: 16 Mar 2024 02:43

Export record

Altmetrics

Contributors

Author: Robin M. Porter
Author: Andreas A. Danopoulos
Author: Gillian Reid ORCID iD
Author: Lisa R. Titcomb

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Library staff additional information
Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×