PS-COD and PS-9-BBN: polymer-supported reagents for solution-phase parallel synthesist

Revell, Jefferson D., Dörner, Barbara, White, Peter D. and Ganesan, A. , Merck Biosciences (2005) PS-COD and PS-9-BBN: polymer-supported reagents for solution-phase parallel synthesist. Organic Letters, 7 (5), 831-833. (doi:10.1021/ol047458g).

Record type: Article

Abstract

1,5-Cyclooctadiene was deprotonated under LICKOR conditions and reacted with Merrifield resin to afford an immobilized cyclooctadiene in high yield. This polymer is effective as a halogen scavenger, while hydroboration leads to a supported 9-BBN analogue. The latter exhibits similar regioselectivity to 9-BBN in olefin hydroboration.

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Published date: 3 March 2005

Keywords: enantioselective borane reductions, organic-synthesis, prochiral ketones, 9-borabicyclononane, scavengers, hydroboration, 9-bbn

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Identifiers

Local EPrints ID: 20896

URI: http://eprints.soton.ac.uk/id/eprint/20896

DOI: doi:10.1021/ol047458g

ISSN: 1523-7060

PURE UUID: 7c529c95-c1e6-445d-86d6-7065e0af168b

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Date deposited: 02 Mar 2006

Last modified: 15 Mar 2024 06:26

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Contributors

Author: Jefferson D. Revell

Author: Barbara Dörner

Author: Peter D. White

Author: A. Ganesan

Corporate Author: Merck Biosciences

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