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PS-COD and PS-9-BBN: polymer-supported reagents for solution-phase parallel synthesist

PS-COD and PS-9-BBN: polymer-supported reagents for solution-phase parallel synthesist
PS-COD and PS-9-BBN: polymer-supported reagents for solution-phase parallel synthesist
1,5-Cyclooctadiene was deprotonated under LICKOR conditions and reacted with Merrifield resin to afford an immobilized cyclooctadiene in high yield. This polymer is effective as a halogen scavenger, while hydroboration leads to a supported 9-BBN analogue. The latter exhibits similar regioselectivity to 9-BBN in olefin hydroboration.
enantioselective borane reductions, organic-synthesis, prochiral ketones, 9-borabicyclononane, scavengers, hydroboration, 9-bbn
1523-7060
831-833
Revell, Jefferson D.
f0270c0c-fa38-42ab-85a1-4cb1738b91e5
Dörner, Barbara
2bd228fa-0ea0-41d9-96cf-2c36d0ae67ef
White, Peter D.
d33665ca-e96f-4f8b-b016-a9a7e845f7c3
Ganesan, A.
62aa5a87-9308-4383-8686-99726b6bcfb9
Merck Biosciences
Revell, Jefferson D.
f0270c0c-fa38-42ab-85a1-4cb1738b91e5
Dörner, Barbara
2bd228fa-0ea0-41d9-96cf-2c36d0ae67ef
White, Peter D.
d33665ca-e96f-4f8b-b016-a9a7e845f7c3
Ganesan, A.
62aa5a87-9308-4383-8686-99726b6bcfb9

Revell, Jefferson D., Dörner, Barbara, White, Peter D. and Ganesan, A. , Merck Biosciences (2005) PS-COD and PS-9-BBN: polymer-supported reagents for solution-phase parallel synthesist. Organic Letters, 7 (5), 831-833. (doi:10.1021/ol047458g).

Record type: Article

Abstract

1,5-Cyclooctadiene was deprotonated under LICKOR conditions and reacted with Merrifield resin to afford an immobilized cyclooctadiene in high yield. This polymer is effective as a halogen scavenger, while hydroboration leads to a supported 9-BBN analogue. The latter exhibits similar regioselectivity to 9-BBN in olefin hydroboration.

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More information

Published date: 3 March 2005
Keywords: enantioselective borane reductions, organic-synthesis, prochiral ketones, 9-borabicyclononane, scavengers, hydroboration, 9-bbn

Identifiers

Local EPrints ID: 20896
URI: http://eprints.soton.ac.uk/id/eprint/20896
ISSN: 1523-7060
PURE UUID: 7c529c95-c1e6-445d-86d6-7065e0af168b

Catalogue record

Date deposited: 02 Mar 2006
Last modified: 15 Jul 2019 19:25

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Contributors

Author: Jefferson D. Revell
Author: Barbara Dörner
Author: Peter D. White
Author: A. Ganesan
Corporate Author: Merck Biosciences

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