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Microstructural studies of copper incorporated amorphous carbon nitride films

Microstructural studies of copper incorporated amorphous carbon nitride films
Microstructural studies of copper incorporated amorphous carbon nitride films
The effects of the incorporation of copper on the microstructure of amorphous carbon nitride films has been studied. Copper incorporated amorphous carbon nitride films (a-C : N : Cu) with different copper concentrations have been prepared by a magnetron co-sputtering technique. Both X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) have been used to characterise the bonding structures in the films. It is found that the N/(N+C) atomic ratio increases due to the incorporation of copper. The results also show that copper incorporation promotes formation of the sp3-bonded carbon nitrogen phase. The diamond nucleation in a-C : N : Cu films, which is determined from the observation of two-phonon diamond absorption FTIR bands, has been ascribed to the favorable formation of the sp3-bonded carbon nitrogen phase in the a-C : N : Cu films.
61.43.Dq, 68.55.Nq, S7.14
0031-8965
203-207
Jiang, Liudi
374f2414-51f0-418f-a316-e7db0d6dc4d1
Fitzgerald, A.G.
a25c0ee4-638b-47b5-987e-cd8969e29345
Rose, M.J.
bd6c0b8a-1e4e-4ce8-be63-6c0bb1cc59a4
Jiang, Liudi
374f2414-51f0-418f-a316-e7db0d6dc4d1
Fitzgerald, A.G.
a25c0ee4-638b-47b5-987e-cd8969e29345
Rose, M.J.
bd6c0b8a-1e4e-4ce8-be63-6c0bb1cc59a4

Jiang, Liudi, Fitzgerald, A.G. and Rose, M.J. (2002) Microstructural studies of copper incorporated amorphous carbon nitride films. Physica Status Solidi A-Applied Research, 189 (1), 203-207. (doi:10.1002/1521-396X(200201)189:1<203::AID-PSSA203>3.0.CO;2-D).

Record type: Article

Abstract

The effects of the incorporation of copper on the microstructure of amorphous carbon nitride films has been studied. Copper incorporated amorphous carbon nitride films (a-C : N : Cu) with different copper concentrations have been prepared by a magnetron co-sputtering technique. Both X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) have been used to characterise the bonding structures in the films. It is found that the N/(N+C) atomic ratio increases due to the incorporation of copper. The results also show that copper incorporation promotes formation of the sp3-bonded carbon nitrogen phase. The diamond nucleation in a-C : N : Cu films, which is determined from the observation of two-phonon diamond absorption FTIR bands, has been ascribed to the favorable formation of the sp3-bonded carbon nitrogen phase in the a-C : N : Cu films.

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More information

Published date: 2002
Keywords: 61.43.Dq, 68.55.Nq, S7.14

Identifiers

Local EPrints ID: 23551
URI: http://eprints.soton.ac.uk/id/eprint/23551
ISSN: 0031-8965
PURE UUID: ff2f79f2-3e27-4997-b90f-64ef3abd36fa
ORCID for Liudi Jiang: ORCID iD orcid.org/0000-0002-3400-825X

Catalogue record

Date deposited: 28 Mar 2006
Last modified: 16 Mar 2024 03:47

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Contributors

Author: Liudi Jiang ORCID iD
Author: A.G. Fitzgerald
Author: M.J. Rose

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