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A novel flow battery: a lead acid battery based on an electrolyte with soluble lead(II). Part III: the influence of conditions on battery performance

A novel flow battery: a lead acid battery based on an electrolyte with soluble lead(II). Part III: the influence of conditions on battery performance
A novel flow battery: a lead acid battery based on an electrolyte with soluble lead(II). Part III: the influence of conditions on battery performance
The performance of an undivided flow battery based on the Pb(II)/Pb and PbO2/Pb(II) couples in aqueous methanesulfonic acid as a function of state of charge, current density, electrolyte flow rate and temperature is reported. In addition, it is demonstrated that the cell chemistry can be rebalanced after multiple charge/discharge by allowing the excess lead metal deposited at the negative electrode to react with oxygen on open circuit.
flow batteries, lead acid, methanesulfonic acid
0378-7753
96-102
Pletcher, Derek
f22ebe69-b859-4a89-80b0-9e190e6f8f30
Wills, Richard
60b7c98f-eced-4b11-aad9-fd2484e26c2c
Pletcher, Derek
f22ebe69-b859-4a89-80b0-9e190e6f8f30
Wills, Richard
60b7c98f-eced-4b11-aad9-fd2484e26c2c

Pletcher, Derek and Wills, Richard (2005) A novel flow battery: a lead acid battery based on an electrolyte with soluble lead(II). Part III: the influence of conditions on battery performance. Journal of Power Sources, 149, 96-102. (doi:10.1016/j.jpowsour.2005.01.048).

Record type: Article

Abstract

The performance of an undivided flow battery based on the Pb(II)/Pb and PbO2/Pb(II) couples in aqueous methanesulfonic acid as a function of state of charge, current density, electrolyte flow rate and temperature is reported. In addition, it is demonstrated that the cell chemistry can be rebalanced after multiple charge/discharge by allowing the excess lead metal deposited at the negative electrode to react with oxygen on open circuit.

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Published date: 2005
Keywords: flow batteries, lead acid, methanesulfonic acid
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Identifiers

Local EPrints ID: 23587
URI: http://eprints.soton.ac.uk/id/eprint/23587
DOI: doi:10.1016/j.jpowsour.2005.01.048
ISSN: 0378-7753
PURE UUID: b25c4bf8-e9f6-4ecd-bdbd-fe6efac0098d
ORCID for Richard Wills: ORCID iD orcid.org/0000-0002-4805-7589

Catalogue record

Date deposited: 20 Mar 2006
Last modified: 16 Mar 2024 03:34

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Contributors

Author: Derek Pletcher
Author: Richard Wills ORCID iD

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