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Theory of the order parameter in NaNO2 in the molecular field approximation

Bonilla, I.R., Holz, A. and Rutt, H.N. (1974) Theory of the order parameter in NaNO2 in the molecular field approximation Physica Status Solidi, 63, (1), pp. 297-305.

Record type: Article

Abstract

A static theory of the order-disorder, ferro-paraelectric phase transition in NaNO2 is developed. The Coulomb energy of the system is calculated in the point charge approximation. The model takes the relative displacement ?°(T) of the Na+ ions from their symmetrical position as a function of temperature into account; and the strong correlation of the Na+ ion position with the dipole orientation of the neighboring NO2? ion. The short range force potential acting on the Na+ ion is fitted by means of ?°(0) which can be taken from experiment. The long-range order parameter ? is calculated in the molecular field approximation. A first order phase transition is obtained for which the critical values Tc and ?c are calculated as a function of the permanent electric dipole moment of NO2? and ?°(0). Only qualitative agreement with experimental results is obtained. The Made-lung constant of the lattice is obtained as ? = 1.93.

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Published date: May 1974
Organisations: Electronics & Computer Science

Identifiers

Local EPrints ID: 258458
URI: http://eprints.soton.ac.uk/id/eprint/258458
PURE UUID: 9c7790a0-c0ce-41c9-84ea-afb59c624f2e

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Date deposited: 05 Nov 2003
Last modified: 18 Jul 2017 09:32

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Contributors

Author: I.R. Bonilla
Author: A. Holz
Author: H.N. Rutt

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