Coleman, A.P., Nieuwenhuyzen, M., Rutt, H.N. and Seddon, K.R.
Novel Ionic Media for Liquid Lasers
Journal of the Chemical Society, Chemical Communications, 23, .
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In a search for 3-5 ?m lasing materials, crystals Of AlBr6Sb are isolated from a phosphorus tribromide-aluminium tribromide-antimony tribromide (PBr3-AlBr3-SbBr3) solution: this solid contains infinite chains of alternating [SbBr2]+ cations and [AlBr4]+ anions, linked by weak coordinate bonds, and represents the first structure containing the dibromostibinium(III) cation.
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