Amorphous "Ti3N4" and formation of nanocrystalline TiN
Amorphous "Ti3N4" and formation of nanocrystalline TiN
The existence of Ti3N4 was proposed as the first product of the thermal decomposition of precipitates obtained in ammonolysis reactions of titanium(IV) dialkylamides. The evidence is re-evaluated and further evidence is presented to demonstrate that these materials are probably TiN contaminated with carbon. However, this precursor system is demonstrated to be a good route to finely divided, nanocrystalline TiN powders.
Hector, Andrew L.
f19a8f31-b37f-4474-b32a-b7cf05b9f0e5
Jackson, Andrew W.
049d4dbf-e5c9-4b4a-b5ae-bd16cd1b923b
McMillan, Paul F.
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Shebanova, Olga
e6580f7d-d9f0-48b1-84b1-43a2d6e9699e
Li, Jing
fafa4088-5b81-4c81-9228-ae4da619d9ff
Brese, Nathaniel E.
a78b44df-79a6-4933-948a-ca40220addf2
Kanatzidis, Mercouri G.
ee843e54-1d9e-48ef-a31a-c65304889a60
Jansen, Martin
6fcd066d-6110-49ce-ac2c-c6a7b65d324e
13 January 2005
Hector, Andrew L.
f19a8f31-b37f-4474-b32a-b7cf05b9f0e5
Jackson, Andrew W.
049d4dbf-e5c9-4b4a-b5ae-bd16cd1b923b
McMillan, Paul F.
8bca9219-06e0-4621-bdae-ad059709a147
Shebanova, Olga
e6580f7d-d9f0-48b1-84b1-43a2d6e9699e
Li, Jing
fafa4088-5b81-4c81-9228-ae4da619d9ff
Brese, Nathaniel E.
a78b44df-79a6-4933-948a-ca40220addf2
Kanatzidis, Mercouri G.
ee843e54-1d9e-48ef-a31a-c65304889a60
Jansen, Martin
6fcd066d-6110-49ce-ac2c-c6a7b65d324e
Hector, Andrew L., Jackson, Andrew W., McMillan, Paul F. and Shebanova, Olga
,
Li, Jing, Brese, Nathaniel E., Kanatzidis, Mercouri G. and Jansen, Martin
(eds.)
(2005)
Amorphous "Ti3N4" and formation of nanocrystalline TiN.
Materials Research Society Symposium Proceedings, 848.
Abstract
The existence of Ti3N4 was proposed as the first product of the thermal decomposition of precipitates obtained in ammonolysis reactions of titanium(IV) dialkylamides. The evidence is re-evaluated and further evidence is presented to demonstrate that these materials are probably TiN contaminated with carbon. However, this precursor system is demonstrated to be a good route to finely divided, nanocrystalline TiN powders.
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Published date: 13 January 2005
Additional Information:
Page range: FF.2.3.1 - FF2.3.5
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Local EPrints ID: 28670
URI: http://eprints.soton.ac.uk/id/eprint/28670
PURE UUID: 1432709b-9c9c-4ab2-adc0-d46337f19432
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Date deposited: 08 May 2006
Last modified: 08 Jan 2022 02:44
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Contributors
Author:
Andrew W. Jackson
Author:
Paul F. McMillan
Author:
Olga Shebanova
Editor:
Jing Li
Editor:
Nathaniel E. Brese
Editor:
Mercouri G. Kanatzidis
Editor:
Martin Jansen
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