Development of a new photoelectron spectroscopy instrument combining an electrospray ion source and photoelectron imaging
Development of a new photoelectron spectroscopy instrument combining an electrospray ion source and photoelectron imaging
A new apparatus has been constructed that combines electrospray ionization with a quadrupole mass filter, hexapole ion trap, and velocity-map imaging. The purpose is to record photoelectron images of isolated chromophore anions. To demonstrate the capability of our instrument we have recorded the photodetachment spectra of isolated deprotonated phenol and indole anions. To our knowledge, this is the first time that the photodetachment energy of the deprotonated indole anion has been recorded
123101-1-123101-9
McKay, A.R.
c3e1e69f-cdd3-44c4-afd2-9f649ce9aaea
Sanz, M.E.
83465137-9c29-4fc6-82cd-18bd9e431ba8
Mooney, C.R.S.
b18f5e22-7b62-470d-a413-382cd9734a6c
Minns, R.S.
85280db4-c5a6-4a4c-82fe-75693c6a6045
Gill, E.M.
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Fielding, H.H.
02d57d59-c588-4c85-98de-cc74e7325649
14 December 2010
McKay, A.R.
c3e1e69f-cdd3-44c4-afd2-9f649ce9aaea
Sanz, M.E.
83465137-9c29-4fc6-82cd-18bd9e431ba8
Mooney, C.R.S.
b18f5e22-7b62-470d-a413-382cd9734a6c
Minns, R.S.
85280db4-c5a6-4a4c-82fe-75693c6a6045
Gill, E.M.
b7b07e89-859e-48f1-9a3e-3e7f823c35b3
Fielding, H.H.
02d57d59-c588-4c85-98de-cc74e7325649
McKay, A.R., Sanz, M.E., Mooney, C.R.S., Minns, R.S., Gill, E.M. and Fielding, H.H.
(2010)
Development of a new photoelectron spectroscopy instrument combining an electrospray ion source and photoelectron imaging.
Review of Scientific Instruments, 81 (12), .
(doi:10.1063/1.3505097).
Abstract
A new apparatus has been constructed that combines electrospray ionization with a quadrupole mass filter, hexapole ion trap, and velocity-map imaging. The purpose is to record photoelectron images of isolated chromophore anions. To demonstrate the capability of our instrument we have recorded the photodetachment spectra of isolated deprotonated phenol and indole anions. To our knowledge, this is the first time that the photodetachment energy of the deprotonated indole anion has been recorded
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Published date: 14 December 2010
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Times Cited: 1
Organisations:
Chemistry
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Local EPrints ID: 336631
URI: http://eprints.soton.ac.uk/id/eprint/336631
ISSN: 0034-6748
PURE UUID: a23a5e66-c7a8-463a-ac6d-38b4d6ff0884
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Date deposited: 02 Apr 2012 12:57
Last modified: 15 Mar 2024 03:40
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Contributors
Author:
A.R. McKay
Author:
M.E. Sanz
Author:
C.R.S. Mooney
Author:
E.M. Gill
Author:
H.H. Fielding
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