The University of Southampton
University of Southampton Institutional Repository

Observation of the Stark effect in upsilon(+)=0 Rydberg states of NO: a comparison between predissociating and bound states

Observation of the Stark effect in upsilon(+)=0 Rydberg states of NO: a comparison between predissociating and bound states
Observation of the Stark effect in upsilon(+)=0 Rydberg states of NO: a comparison between predissociating and bound states
The Stark spectra of Rydberg states of NO below the ?+ = 0 ionization limit, with principal quantum numbers n = 25–30, have been investigated in the presence of dc electric fields in the range 0–150 V cm?1. The Stark states were accessed by two-colour, double-resonance excitation via the ?' = 0, N' = 0 rovibrational state of the A2?+ state. The N(2D) atoms produced by predissociation were measured by (2 + 1) resonance-enhanced multiphoton ionization, and compared with pulsed-field ionization spectra of the bound Rydberg state population (Patel et al 2007 J. Phys. B: At. Mol. Opt. Phys. 40 1369).


multiphoton ionization and excitation to highly excited states, autoionization, photoionization and photodetachment, Diffuse spectra, predissociation, photodissociation
Jones, N.J.A.
73b7b20e-07fe-4f40-ac5d-5f946e7c2152
Minns, R.S.
85280db4-c5a6-4a4c-82fe-75693c6a6045
Patel, R.
ec08d4e1-fc72-4d22-9f47-2bc83a475b1c
Fielding, H.H.
02d57d59-c588-4c85-98de-cc74e7325649
Jones, N.J.A.
73b7b20e-07fe-4f40-ac5d-5f946e7c2152
Minns, R.S.
85280db4-c5a6-4a4c-82fe-75693c6a6045
Patel, R.
ec08d4e1-fc72-4d22-9f47-2bc83a475b1c
Fielding, H.H.
02d57d59-c588-4c85-98de-cc74e7325649

Jones, N.J.A., Minns, R.S., Patel, R. and Fielding, H.H. (2008) Observation of the Stark effect in upsilon(+)=0 Rydberg states of NO: a comparison between predissociating and bound states. Journal of Physics B-Atomic Molecular and Optical Physics, 41 (18). (doi:10.1088/0953-4075/41/18/185102).

Record type: Article

Abstract

The Stark spectra of Rydberg states of NO below the ?+ = 0 ionization limit, with principal quantum numbers n = 25–30, have been investigated in the presence of dc electric fields in the range 0–150 V cm?1. The Stark states were accessed by two-colour, double-resonance excitation via the ?' = 0, N' = 0 rovibrational state of the A2?+ state. The N(2D) atoms produced by predissociation were measured by (2 + 1) resonance-enhanced multiphoton ionization, and compared with pulsed-field ionization spectra of the bound Rydberg state population (Patel et al 2007 J. Phys. B: At. Mol. Opt. Phys. 40 1369).


Full text not available from this repository.

More information

Published date: 2 September 2008
Additional Information: 185102, Times Cited: 1
Keywords: multiphoton ionization and excitation to highly excited states, autoionization, photoionization and photodetachment, Diffuse spectra, predissociation, photodissociation
Organisations: Chemistry

Identifiers

Local EPrints ID: 336635
URI: http://eprints.soton.ac.uk/id/eprint/336635
PURE UUID: c057821d-5db3-4b69-a837-79184792f4f6
ORCID for R.S. Minns: ORCID iD orcid.org/0000-0001-6775-2977

Catalogue record

Date deposited: 02 Apr 2012 11:17
Last modified: 07 Oct 2020 02:00

Export record

Altmetrics

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×