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Optical control of the rotational angular momentum of a molecular Rydberg wave packet

Optical control of the rotational angular momentum of a molecular Rydberg wave packet
Optical control of the rotational angular momentum of a molecular Rydberg wave packet
An intuitive scheme for controlling the rotational quantum state of a Rydberg molecule is demonstrated experimentally. We determine the accumulated phase difference between the various components of a molecular electron wave packet, and then employ a sequence of phase-locked optical pulses to selectively enhance or depopulate specific rotational states. The angular momentum composition of the resulting wave packet, and the efficiency of the control scheme, is determined by calculating the multipulse response of the time-dependent Rydberg populations
243601-[4 pages]
Minns, R.S.
f110808e-17e4-466d-8271-7a680ba46c65
Patel, R.
ec08d4e1-fc72-4d22-9f47-2bc83a475b1c
Verlet, J.R.R.
740dcfb2-46bd-4dc6-80f8-b06fd437d693
Fielding, H. H.
e864e514-937d-4eb8-bfb6-ca71630424f3
Minns, R.S.
f110808e-17e4-466d-8271-7a680ba46c65
Patel, R.
ec08d4e1-fc72-4d22-9f47-2bc83a475b1c
Verlet, J.R.R.
740dcfb2-46bd-4dc6-80f8-b06fd437d693
Fielding, H. H.
e864e514-937d-4eb8-bfb6-ca71630424f3

Minns, R.S., Patel, R., Verlet, J.R.R. and Fielding, H. H. (2003) Optical control of the rotational angular momentum of a molecular Rydberg wave packet. Physical Review Letters, 91 (24), 243601-[4 pages]. (doi:10.1103/PhysRevLett.91.243601).

Record type: Article

Abstract

An intuitive scheme for controlling the rotational quantum state of a Rydberg molecule is demonstrated experimentally. We determine the accumulated phase difference between the various components of a molecular electron wave packet, and then employ a sequence of phase-locked optical pulses to selectively enhance or depopulate specific rotational states. The angular momentum composition of the resulting wave packet, and the efficiency of the control scheme, is determined by calculating the multipulse response of the time-dependent Rydberg populations

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More information

Published date: December 2003
Additional Information: Times Cited: 26
Organisations: Chemistry

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Local EPrints ID: 336640
URI: http://eprints.soton.ac.uk/id/eprint/336640
PURE UUID: 9b5a25d1-97e3-4c6d-a220-8ad8c89583be

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Date deposited: 11 Apr 2012 08:47
Last modified: 14 Mar 2024 10:45

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Contributors

Author: R.S. Minns
Author: R. Patel
Author: J.R.R. Verlet
Author: H. H. Fielding

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