Binaphthyl platform as starting materials for the preparation of electron rich benzo[g,h,i]perylenes. Application to molecular architectures based on amino benzo[g,h,i]perylenes and carborane combinations

Pieters, Grégory, Gaucher, Anne, Prim, Damien, Besson, Thierry, Giner Planas, José, Teixidor, Francesc, Viñas, Clara, Light, Mark E. and Hursthouse, Michael B. (2011) Binaphthyl platform as starting materials for the preparation of electron rich benzo[g,h,i]perylenes. Application to molecular architectures based on amino benzo[g,h,i]perylenes and carborane combinations. Chemical Communications, 47 (27), 7725-7727. (doi:10.1039/c1cc12099a).

Abstract

Valuable amino benzo[g,h,i]perylenes have been obtained through a one pot electrophilic aromatic substitution—Scholl reaction sequence. Novel molecular architectures combining 3D-o-carborane and planar amino benzo[g,h,i]perylene units are described. Photophysical properties of amino benzo[g,h,i]perylene and the carborane-appended derivatives are discussed

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Contributors

Author: Mark E. Light

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