A chiral ferromagnetic molecular metal
A chiral ferromagnetic molecular metal
The first molecular material with the coexistence of ferromagnetism, metal-like conductivity, and chirality has been prepared using an organic/inorganic approach. In this case, a two-dimensional packing of chiral organic radical cations (responsible for both the electrical conductivity and optical activity) was assembled with a layered bimetallic oxalate-based anionic network (responsible for the magnetic properties). Shubnikov?de Haas oscillations confirmed the presence of a Fermi surface even when the transport properties suggested “insulating”-type behavior at very low temperatures
9271-9273
Galán-Mascarós, José R.
816f8030-d13a-4235-b2e6-90b0313abf2e
Coronado, Eugenio
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Goddard, Paul A.
1fe858e1-174d-4417-9430-1ced4f4e8800
Singleton, John
a7087c94-3daa-4ba8-874c-ef5568ae3ee6
Coldea, Amalia I.
298024fa-43b5-4619-83d8-6991cd49cfa1
Wallis, John D.
bc777046-08c0-40bf-9cfd-3a69481bb06a
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Alberola, Antonio
d714c270-0df8-44df-bdcc-1af0d5717c44
2010
Galán-Mascarós, José R.
816f8030-d13a-4235-b2e6-90b0313abf2e
Coronado, Eugenio
5056e1ee-c4c8-4f17-95a0-45edf98bc160
Goddard, Paul A.
1fe858e1-174d-4417-9430-1ced4f4e8800
Singleton, John
a7087c94-3daa-4ba8-874c-ef5568ae3ee6
Coldea, Amalia I.
298024fa-43b5-4619-83d8-6991cd49cfa1
Wallis, John D.
bc777046-08c0-40bf-9cfd-3a69481bb06a
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Alberola, Antonio
d714c270-0df8-44df-bdcc-1af0d5717c44
Galán-Mascarós, José R., Coronado, Eugenio, Goddard, Paul A., Singleton, John, Coldea, Amalia I., Wallis, John D., Coles, Simon J. and Alberola, Antonio
(2010)
A chiral ferromagnetic molecular metal.
Journal of the American Chemical Society, 132 (27), .
(doi:10.1021/ja103147k).
Abstract
The first molecular material with the coexistence of ferromagnetism, metal-like conductivity, and chirality has been prepared using an organic/inorganic approach. In this case, a two-dimensional packing of chiral organic radical cations (responsible for both the electrical conductivity and optical activity) was assembled with a layered bimetallic oxalate-based anionic network (responsible for the magnetic properties). Shubnikov?de Haas oscillations confirmed the presence of a Fermi surface even when the transport properties suggested “insulating”-type behavior at very low temperatures
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e-pub ahead of print date: 10 June 2010
Published date: 2010
Organisations:
Organic Chemistry: Synthesis, Catalysis and Flow
Identifiers
Local EPrints ID: 336803
URI: http://eprints.soton.ac.uk/id/eprint/336803
ISSN: 0002-7863
PURE UUID: a0dd2ff0-9ff4-4d4f-b760-aac075d311ae
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Date deposited: 11 Apr 2012 10:31
Last modified: 15 Mar 2024 03:01
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Contributors
Author:
José R. Galán-Mascarós
Author:
Eugenio Coronado
Author:
Paul A. Goddard
Author:
John Singleton
Author:
Amalia I. Coldea
Author:
John D. Wallis
Author:
Antonio Alberola
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