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Towards conformationally dependent redox-responsive molecular switches. New polyferrocene bis benzo crown ether receptors

Towards conformationally dependent redox-responsive molecular switches. New polyferrocene bis benzo crown ether receptors
Towards conformationally dependent redox-responsive molecular switches. New polyferrocene bis benzo crown ether receptors
New polyferrocene bis benzo-15-crown-5 ligands have been prepared and shown to form 1:1 intramolecular sandwich complexes with the potassium cation. Electrochemical investigations reveal that both receptors undergo small anodic perturbations of the respective ferrocene-ferrocenium redox couples in the presence of alkali metal cations.
iron, polyferrocene, crown ethers, molecular switches, redox couples, potassium complexes
0022-328X
143-148
Beer, Paul D.
6af15407-244d-4e11-8147-a62a04672f4e
Crane, Christopher G.
cac1a02f-e7c7-4be6-9157-0bddf08320da
Danks, Jonathan P.
8bcd23eb-9fb0-4005-a3bf-fadbdff63130
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
McAleer, Jerome F.
40138995-5633-46c4-af2c-0a33f62027ab
Beer, Paul D.
6af15407-244d-4e11-8147-a62a04672f4e
Crane, Christopher G.
cac1a02f-e7c7-4be6-9157-0bddf08320da
Danks, Jonathan P.
8bcd23eb-9fb0-4005-a3bf-fadbdff63130
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
McAleer, Jerome F.
40138995-5633-46c4-af2c-0a33f62027ab

(1995) Towards conformationally dependent redox-responsive molecular switches. New polyferrocene bis benzo crown ether receptors. Journal of Organometallic Chemistry, 490 (1-2), 143-148. (doi:10.1016/0022-328X(94)05191-D).

Record type: Article

Abstract

New polyferrocene bis benzo-15-crown-5 ligands have been prepared and shown to form 1:1 intramolecular sandwich complexes with the potassium cation. Electrochemical investigations reveal that both receptors undergo small anodic perturbations of the respective ferrocene-ferrocenium redox couples in the presence of alkali metal cations.

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More information

Published date: 22 March 1995
Keywords: iron, polyferrocene, crown ethers, molecular switches, redox couples, potassium complexes
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 337249
URI: http://eprints.soton.ac.uk/id/eprint/337249
DOI: doi:10.1016/0022-328X(94)05191-D
ISSN: 0022-328X
PURE UUID: 47ff9d50-53fb-455f-8fd4-f18457512c78
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910

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Date deposited: 20 Apr 2012 14:29
Last modified: 06 Jun 2018 12:52

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Contributors

Author: Paul D. Beer
Author: Christopher G. Crane
Author: Jonathan P. Danks
Author: Philip A. Gale ORCID iD
Author: Jerome F. McAleer

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