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Towards conformationally dependent redox-responsive molecular switches. New polyferrocene bis benzo crown ether receptors

Beer, Paul D., Crane, Christopher G., Danks, Jonathan P., Gale, Philip A. and McAleer, Jerome F. (1995) Towards conformationally dependent redox-responsive molecular switches. New polyferrocene bis benzo crown ether receptors Journal of Organometallic Chemistry, 490, (1-2), pp. 143-148. (doi:10.1016/0022-328X(94)05191-D).

Record type: Article

Abstract

New polyferrocene bis benzo-15-crown-5 ligands have been prepared and shown to form 1:1 intramolecular sandwich complexes with the potassium cation. Electrochemical investigations reveal that both receptors undergo small anodic perturbations of the respective ferrocene-ferrocenium redox couples in the presence of alkali metal cations.

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More information

Published date: 22 March 1995
Keywords: iron, polyferrocene, crown ethers, molecular switches, redox couples, potassium complexes
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 337249
URI: http://eprints.soton.ac.uk/id/eprint/337249
DOI: doi:10.1016/0022-328X(94)05191-D
ISSN: 0022-328X
PURE UUID: 47ff9d50-53fb-455f-8fd4-f18457512c78
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910

Catalogue record

Date deposited: 20 Apr 2012 14:29
Last modified: 18 Jul 2017 06:04

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Contributors

Author: Paul D. Beer
Author: Christopher G. Crane
Author: Jonathan P. Danks
Author: Philip A. Gale ORCID iD
Author: Jerome F. McAleer

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