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Towards conformationally dependent redox-responsive molecular switches. New polyferrocene bis benzo crown ether receptors

Record type: Article

New polyferrocene bis benzo-15-crown-5 ligands have been prepared and shown to form 1:1 intramolecular sandwich complexes with the potassium cation. Electrochemical investigations reveal that both receptors undergo small anodic perturbations of the respective ferrocene-ferrocenium redox couples in the presence of alkali metal cations.

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Citation

Beer, Paul D., Crane, Christopher G., Danks, Jonathan P., Gale, Philip A. and McAleer, Jerome F. (1995) Towards conformationally dependent redox-responsive molecular switches. New polyferrocene bis benzo crown ether receptors Journal of Organometallic Chemistry, 490, (1-2), pp. 143-148. (doi:10.1016/0022-328X(94)05191-D).

More information

Published date: 22 March 1995
Keywords: iron, polyferrocene, crown ethers, molecular switches, redox couples, potassium complexes
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 337249
URI: http://eprints.soton.ac.uk/id/eprint/337249
ISSN: 0022-328X
PURE UUID: 47ff9d50-53fb-455f-8fd4-f18457512c78
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910

Catalogue record

Date deposited: 20 Apr 2012 14:29
Last modified: 18 Jul 2017 06:04

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Contributors

Author: Paul D. Beer
Author: Christopher G. Crane
Author: Jonathan P. Danks
Author: Philip A. Gale ORCID iD
Author: Jerome F. McAleer

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