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Anion binding: self-assembly of polypyrrolic macrocycles

Anion binding: self-assembly of polypyrrolic macrocycles
Anion binding: self-assembly of polypyrrolic macrocycles
Anion complexation drives the self-assembly of appropriately designed macrocycles (sapphyrin and/or calix[4]pyrrole) containing pendant carboxylic arms (black in the schematic representation on the right). The self-assembly process can be disrupted by addition of F? ions (sapphyrin) or in the case of calix[4]pyrrole, polar solvents.
anion binding, calixarenes, sapphyrin, self-assembly
1433-7851
2782-2785
Sessler, Jonathan L.
d793ea76-a3a2-4ce1-a8d5-aca7d3307fbe
Andrievsky, Andrei
2f6c34f2-24ba-4d3d-89c3-a3bbb933e83f
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Lynch, Vincent
f3e8eebc-c5fd-4c4d-9cb3-a44e24ca204d
Sessler, Jonathan L.
d793ea76-a3a2-4ce1-a8d5-aca7d3307fbe
Andrievsky, Andrei
2f6c34f2-24ba-4d3d-89c3-a3bbb933e83f
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Lynch, Vincent
f3e8eebc-c5fd-4c4d-9cb3-a44e24ca204d

Sessler, Jonathan L., Andrievsky, Andrei, Gale, Philip A. and Lynch, Vincent (1996) Anion binding: self-assembly of polypyrrolic macrocycles. Angewandte Chemie International Edition, 35 (23-24), 2782-2785. (doi:10.1002/anie.199627821).

Record type: Article

Abstract

Anion complexation drives the self-assembly of appropriately designed macrocycles (sapphyrin and/or calix[4]pyrrole) containing pendant carboxylic arms (black in the schematic representation on the right). The self-assembly process can be disrupted by addition of F? ions (sapphyrin) or in the case of calix[4]pyrrole, polar solvents.

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More information

Published date: December 1996
Keywords: anion binding, calixarenes, sapphyrin, self-assembly
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 337257
URI: http://eprints.soton.ac.uk/id/eprint/337257
DOI: doi:10.1002/anie.199627821
ISSN: 1433-7851
PURE UUID: 36d3ec3c-d9f2-4381-963c-f08a6c685b4e
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910

Catalogue record

Date deposited: 20 Apr 2012 13:12
Last modified: 15 Mar 2024 03:06

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Contributors

Author: Jonathan L. Sessler
Author: Andrei Andrievsky
Author: Philip A. Gale ORCID iD
Author: Vincent Lynch

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