Sessler, Jonathan L., Andrievsky, Andrei, Gale, Philip A. and Lynch, Vincent
Anion binding: self-assembly of polypyrrolic macrocycles
Angewandte Chemie International Edition, 35, (23-24), . (doi:10.1002/anie.199627821).
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Anion complexation drives the self-assembly of appropriately designed macrocycles (sapphyrin and/or calixpyrrole) containing pendant carboxylic arms (black in the schematic representation on the right). The self-assembly process can be disrupted by addition of F? ions (sapphyrin) or in the case of calixpyrrole, polar solvents.
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