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The methoxylation of N-formylpyrrolidine in a microfluidic electrolysis cell for routine synthesis

The methoxylation of N-formylpyrrolidine in a microfluidic electrolysis cell for routine synthesis
The methoxylation of N-formylpyrrolidine in a microfluidic electrolysis cell for routine synthesis
A single channel microfluidic electrolysis cell being developed for application alongside other routine microfluidic operations in the laboratory has been applied to the methoxylation of N-formylpyrrolidine. It is shown that very high conversions (?90%) in a single pass can be achieved and it is possible to obtain several grams of product per hour with a good selectivity in optimised conditions.
microflow reactor, electrolysis cell, methoxylation reactions, oxidation
0013-4686
197-202
Kuleshova, Jekaterina
95594d04-c0e8-4a1f-b5cf-b3f90b314dd6
Hill-Cousins, Joseph T.
3fd2a389-1612-4d9d-8322-afcc0c401ada
Birkin, Peter R.
ba466560-f27c-418d-89fc-67ea4f81d0a7
Brown, Richard C.D.
21ce697a-7c3a-480e-919f-429a3d8550f5
Pletcher, Derek
f22ebe69-b859-4a89-80b0-9e190e6f8f30
Underwood, Toby J.
3cc077da-ea35-47d2-83cc-138b4c2d531d
Kuleshova, Jekaterina
95594d04-c0e8-4a1f-b5cf-b3f90b314dd6
Hill-Cousins, Joseph T.
3fd2a389-1612-4d9d-8322-afcc0c401ada
Birkin, Peter R.
ba466560-f27c-418d-89fc-67ea4f81d0a7
Brown, Richard C.D.
21ce697a-7c3a-480e-919f-429a3d8550f5
Pletcher, Derek
f22ebe69-b859-4a89-80b0-9e190e6f8f30
Underwood, Toby J.
3cc077da-ea35-47d2-83cc-138b4c2d531d

Kuleshova, Jekaterina, Hill-Cousins, Joseph T., Birkin, Peter R., Brown, Richard C.D., Pletcher, Derek and Underwood, Toby J. (2012) The methoxylation of N-formylpyrrolidine in a microfluidic electrolysis cell for routine synthesis. Electrochimica Acta, 69, 197-202. (doi:10.1016/j.electacta.2012.02.093).

Record type: Article

Abstract

A single channel microfluidic electrolysis cell being developed for application alongside other routine microfluidic operations in the laboratory has been applied to the methoxylation of N-formylpyrrolidine. It is shown that very high conversions (?90%) in a single pass can be achieved and it is possible to obtain several grams of product per hour with a good selectivity in optimised conditions.

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More information

Published date: 1 May 2012
Keywords: microflow reactor, electrolysis cell, methoxylation reactions, oxidation
Organisations: Chemistry

Identifiers

Local EPrints ID: 337331
URI: http://eprints.soton.ac.uk/id/eprint/337331
ISSN: 0013-4686
PURE UUID: faeaa512-c0f0-4fc9-9a1a-6027efa857f1
ORCID for Peter R. Birkin: ORCID iD orcid.org/0000-0002-6656-4074
ORCID for Richard C.D. Brown: ORCID iD orcid.org/0000-0003-0156-7087

Catalogue record

Date deposited: 24 Apr 2012 12:47
Last modified: 10 Dec 2019 01:55

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