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Solvent templated synthesis of metal-organic frameworks: structural characterisation and properties of the 3D network isomers {[Mn(dcbp)]1/2DMF}n and {[Mn(dcbp)].2H2O}n

Solvent templated synthesis of metal-organic frameworks: structural characterisation and properties of the 3D network isomers {[Mn(dcbp)]1/2DMF}n and {[Mn(dcbp)].2H2O}n
Solvent templated synthesis of metal-organic frameworks: structural characterisation and properties of the 3D network isomers {[Mn(dcbp)]1/2DMF}n and {[Mn(dcbp)].2H2O}n
The identity of the metal–organic framework formed by Mn(II) and 4,4?-dicarboxy-2,2?-bipyridine (H2dcbp) depends upon the predominant solvent employed in the synthesis and yields the robust network isomers {[Mn(dcbp)]·½DMF}n, 1, and {[Mn(dcbp)]·2H2O}n, 2, which possess vastly different physical properties: 1 irretrievably binds DMF, whereas 2 reversibly binds water whilst retaining crystallinity.
1359-7345
776-777
Tynan, Eithne
dfed4bbd-ea2a-4ff9-81f5-de2af563943b
Jensen, Paul
1cfc9b74-1018-4848-9a94-b49afb907651
Kruger, Paul E.
339c2ec3-0e2a-49a1-9af4-44b44ec95e16
Lees, Anthea C.
5e121bd2-91d3-4bb3-a474-f935111b5bef
Tynan, Eithne
dfed4bbd-ea2a-4ff9-81f5-de2af563943b
Jensen, Paul
1cfc9b74-1018-4848-9a94-b49afb907651
Kruger, Paul E.
339c2ec3-0e2a-49a1-9af4-44b44ec95e16
Lees, Anthea C.
5e121bd2-91d3-4bb3-a474-f935111b5bef

Tynan, Eithne, Jensen, Paul, Kruger, Paul E. and Lees, Anthea C. (2004) Solvent templated synthesis of metal-organic frameworks: structural characterisation and properties of the 3D network isomers {[Mn(dcbp)]1/2DMF}n and {[Mn(dcbp)].2H2O}n. Chemical Communications, (7), 776-777. (doi:10.1039/B315483A).

Record type: Article

Abstract

The identity of the metal–organic framework formed by Mn(II) and 4,4?-dicarboxy-2,2?-bipyridine (H2dcbp) depends upon the predominant solvent employed in the synthesis and yields the robust network isomers {[Mn(dcbp)]·½DMF}n, 1, and {[Mn(dcbp)]·2H2O}n, 2, which possess vastly different physical properties: 1 irretrievably binds DMF, whereas 2 reversibly binds water whilst retaining crystallinity.

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Published date: 2004
Organisations: Ocean Biochemistry & Ecosystems

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Local EPrints ID: 339673
URI: http://eprints.soton.ac.uk/id/eprint/339673
ISSN: 1359-7345
PURE UUID: 3c7abf0b-8741-4b78-b887-00d1b14fff37

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Date deposited: 28 May 2012 14:07
Last modified: 16 Jul 2019 22:02

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Contributors

Author: Eithne Tynan
Author: Paul Jensen
Author: Paul E. Kruger
Author: Anthea C. Lees

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