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Highly Z- and enantioselective ring-opening/cross-metathesis reactions and Z-selective ring-opening metathesis polymerization

Highly Z- and enantioselective ring-opening/cross-metathesis reactions and Z-selective ring-opening metathesis polymerization
Highly Z- and enantioselective ring-opening/cross-metathesis reactions and Z-selective ring-opening metathesis polymerization
Stopping the gap: A notable shortcoming in olefin metathesis chemistry was the lack of methods for the selective synthesis of Z?alkenes. A breakthrough has now been achieved by the employment of a new type of chiral Mo complex (see scheme; TBS=tert-butyldimethylsilyl, X=Cl, Br, I). The first examples of the titled reactions are discussed.
alkenes, asymmetric catalysis, enantioselectivity, metathesis, molybdenum
1433-7851
8827-8831
Córdova, Armando
d2a1239f-708d-4f9c-bf7c-c095e9a27cac
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Córdova, Armando
d2a1239f-708d-4f9c-bf7c-c095e9a27cac
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441

Córdova, Armando and Rios, Ramon (2009) Highly Z- and enantioselective ring-opening/cross-metathesis reactions and Z-selective ring-opening metathesis polymerization. Angewandte Chemie International Edition, 48 (47), 8827-8831. (doi:10.1002/anie.200903409). (PMID:19839020)

Record type: Article

Abstract

Stopping the gap: A notable shortcoming in olefin metathesis chemistry was the lack of methods for the selective synthesis of Z?alkenes. A breakthrough has now been achieved by the employment of a new type of chiral Mo complex (see scheme; TBS=tert-butyldimethylsilyl, X=Cl, Br, I). The first examples of the titled reactions are discussed.

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More information

e-pub ahead of print date: 16 October 2009
Published date: 9 November 2009
Keywords: alkenes, asymmetric catalysis, enantioselectivity, metathesis, molybdenum
Organisations: Chemistry

Identifiers

Local EPrints ID: 340217
URI: http://eprints.soton.ac.uk/id/eprint/340217
ISSN: 1433-7851
PURE UUID: 6a2f7c52-62ec-4003-b9dd-a12da2ef650e
ORCID for Ramon Rios: ORCID iD orcid.org/0000-0002-3843-8521

Catalogue record

Date deposited: 15 Jun 2012 11:35
Last modified: 03 Dec 2019 01:38

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