On-off porosity switching in a molecular organic solid
On-off porosity switching in a molecular organic solid
Pulling the old switcheroo: Microporosity can be switched “on” and “off” in a crystalline molecular organic solid composed of cage molecules (see scheme). The switch is facilitated by conformational flexibility in the soft organic crystal state.
conformers, cooperative diffusion, microporous materials, molecular cages
749-753
Jones, James T.A.
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Holden, Daniel
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Mitra, Tamoghna
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Hasell, Tom
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Adams, Dave J.
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Jelfs, Kim E.
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Trewin, Abbie
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Willock, David J.
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Day, Graeme M.
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Bacsa, John
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Steiner, Alexander
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Cooper, Andrew I.
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17 January 2011
Jones, James T.A.
bda2c4c2-7673-4efd-8a88-02d036f2b8db
Holden, Daniel
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Mitra, Tamoghna
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Hasell, Tom
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Adams, Dave J.
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Jelfs, Kim E.
342566a9-c513-43b2-9dee-9eb17ae446c0
Trewin, Abbie
b3c7ad9a-f460-48cd-b532-1a44d69f4854
Willock, David J.
d17cca22-472d-4d1b-91a3-e412008a9ca4
Day, Graeme M.
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Bacsa, John
8877bf1f-d692-4526-b61e-ee3f3c053204
Steiner, Alexander
90c4fb4a-d977-448d-91c6-e38338d4e4d2
Cooper, Andrew I.
95618a3b-7f3f-4731-a0d4-0a7b7ce07302
Jones, James T.A., Holden, Daniel, Mitra, Tamoghna, Hasell, Tom, Adams, Dave J., Jelfs, Kim E., Trewin, Abbie, Willock, David J., Day, Graeme M., Bacsa, John, Steiner, Alexander and Cooper, Andrew I.
(2011)
On-off porosity switching in a molecular organic solid.
Angewandte Chemie International Edition, 50 (3), .
(doi:10.1002/anie.201006030).
Abstract
Pulling the old switcheroo: Microporosity can be switched “on” and “off” in a crystalline molecular organic solid composed of cage molecules (see scheme). The switch is facilitated by conformational flexibility in the soft organic crystal state.
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More information
e-pub ahead of print date: 12 November 2010
Published date: 17 January 2011
Keywords:
conformers, cooperative diffusion, microporous materials, molecular cages
Organisations:
Organic Chemistry: Synthesis, Catalysis and Flow, Chemistry, Computational Systems Chemistry
Identifiers
Local EPrints ID: 343424
URI: http://eprints.soton.ac.uk/id/eprint/343424
ISSN: 1433-7851
PURE UUID: 71e01e6a-9513-4a20-89bc-187c56577c09
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Date deposited: 08 Oct 2012 09:13
Last modified: 15 Mar 2024 03:44
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Contributors
Author:
James T.A. Jones
Author:
Daniel Holden
Author:
Tamoghna Mitra
Author:
Tom Hasell
Author:
Dave J. Adams
Author:
Kim E. Jelfs
Author:
Abbie Trewin
Author:
David J. Willock
Author:
John Bacsa
Author:
Alexander Steiner
Author:
Andrew I. Cooper
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