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On-off porosity switching in a molecular organic solid

On-off porosity switching in a molecular organic solid
On-off porosity switching in a molecular organic solid
Pulling the old switcheroo: Microporosity can be switched “on” and “off” in a crystalline molecular organic solid composed of cage molecules (see scheme). The switch is facilitated by conformational flexibility in the soft organic crystal state.
conformers, cooperative diffusion, microporous materials, molecular cages
1433-7851
749-753
Jones, James T.A.
bda2c4c2-7673-4efd-8a88-02d036f2b8db
Holden, Daniel
fb45b68f-c1d7-44a7-9ec9-eee0fc0373e8
Mitra, Tamoghna
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Hasell, Tom
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Adams, Dave J.
d95e4f11-7580-43cb-802d-ad8ac0161c8a
Jelfs, Kim E.
342566a9-c513-43b2-9dee-9eb17ae446c0
Trewin, Abbie
b3c7ad9a-f460-48cd-b532-1a44d69f4854
Willock, David J.
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Day, Graeme M.
e3be79ba-ad12-4461-b735-74d5c4355636
Bacsa, John
8877bf1f-d692-4526-b61e-ee3f3c053204
Steiner, Alexander
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Cooper, Andrew I.
95618a3b-7f3f-4731-a0d4-0a7b7ce07302
Jones, James T.A.
bda2c4c2-7673-4efd-8a88-02d036f2b8db
Holden, Daniel
fb45b68f-c1d7-44a7-9ec9-eee0fc0373e8
Mitra, Tamoghna
5feb10e3-7bb1-4975-b224-a2069c101a91
Hasell, Tom
6c8f5286-f4e2-456e-a3cd-dcfd3d164e52
Adams, Dave J.
d95e4f11-7580-43cb-802d-ad8ac0161c8a
Jelfs, Kim E.
342566a9-c513-43b2-9dee-9eb17ae446c0
Trewin, Abbie
b3c7ad9a-f460-48cd-b532-1a44d69f4854
Willock, David J.
d17cca22-472d-4d1b-91a3-e412008a9ca4
Day, Graeme M.
e3be79ba-ad12-4461-b735-74d5c4355636
Bacsa, John
8877bf1f-d692-4526-b61e-ee3f3c053204
Steiner, Alexander
90c4fb4a-d977-448d-91c6-e38338d4e4d2
Cooper, Andrew I.
95618a3b-7f3f-4731-a0d4-0a7b7ce07302

Jones, James T.A., Holden, Daniel, Mitra, Tamoghna, Hasell, Tom, Adams, Dave J., Jelfs, Kim E., Trewin, Abbie, Willock, David J., Day, Graeme M., Bacsa, John, Steiner, Alexander and Cooper, Andrew I. (2011) On-off porosity switching in a molecular organic solid. Angewandte Chemie International Edition, 50 (3), 749-753. (doi:10.1002/anie.201006030).

Record type: Article

Abstract

Pulling the old switcheroo: Microporosity can be switched “on” and “off” in a crystalline molecular organic solid composed of cage molecules (see scheme). The switch is facilitated by conformational flexibility in the soft organic crystal state.

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More information

e-pub ahead of print date: 12 November 2010
Published date: 17 January 2011
Keywords: conformers, cooperative diffusion, microporous materials, molecular cages
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow, Chemistry, Computational Systems Chemistry

Identifiers

Local EPrints ID: 343424
URI: http://eprints.soton.ac.uk/id/eprint/343424
ISSN: 1433-7851
PURE UUID: 71e01e6a-9513-4a20-89bc-187c56577c09
ORCID for Graeme M. Day: ORCID iD orcid.org/0000-0001-8396-2771

Catalogue record

Date deposited: 08 Oct 2012 09:13
Last modified: 10 Dec 2019 01:36

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Contributors

Author: James T.A. Jones
Author: Daniel Holden
Author: Tamoghna Mitra
Author: Tom Hasell
Author: Dave J. Adams
Author: Kim E. Jelfs
Author: Abbie Trewin
Author: David J. Willock
Author: Graeme M. Day ORCID iD
Author: John Bacsa
Author: Alexander Steiner
Author: Andrew I. Cooper

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