On-off porosity switching in a molecular organic solid

Jones, James T.A., Holden, Daniel, Mitra, Tamoghna, Hasell, Tom, Adams, Dave J., Jelfs, Kim E., Trewin, Abbie, Willock, David J., Day, Graeme M., Bacsa, John, Steiner, Alexander and Cooper, Andrew I. (2010) On-off porosity switching in a molecular organic solid Angewandte Chemie International Edition, 50, (3), pp. 749-753. (doi:10.1002/anie.201006030).


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Pulling the old switcheroo: Microporosity can be switched “on” and “off” in a crystalline molecular organic solid composed of cage molecules (see scheme). The switch is facilitated by conformational flexibility in the soft organic crystal state.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1002/anie.201006030
ISSNs: 1433-7851 (print)
Keywords: conformers, cooperative diffusion, microporous materials, molecular cages
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow, Chemistry, Computational Systems Chemistry
ePrint ID: 343424
Date :
Date Event
12 November 2010e-pub ahead of print
17 January 2011Published
Date Deposited: 08 Oct 2012 09:13
Last Modified: 17 Apr 2017 16:34
Further Information:Google Scholar
URI: http://eprints.soton.ac.uk/id/eprint/343424

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