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The chemical analysis and replication of polydimethylsiloxane by-products located within electrical trees

The chemical analysis and replication of polydimethylsiloxane by-products located within electrical trees
The chemical analysis and replication of polydimethylsiloxane by-products located within electrical trees
We present a spectroscopic study of electrical trees grown in polydimethylesiloxane (PDMS) rubber. Electrical trees were grown at a range of voltages and allowed to propagate throughout the material. Breakdown and tree channels were exposed using cryogenic microtoming. Raman microprobe spectroscopy (RMS), Fourier Transform Infrared (FTIR), and X-ray Photoelectron Spectroscopy (XPS) were applied in order to obtain a detailed spectroscopic analysis of electrical treeing and breakdown in PDMS rubber.
For comparison, a selection of liquid systems including PDMS oil, dodecylbenzene (DDB) and dodecane (DD) were subjected to ageing via electrical discharges between two electrodes. The debris subsequently formed was subjected to spectroscopic analysis as before. Results are discussed in comparison to previously published results involving electrical treeing and corona discharge experiments in polyethylene (PE) and PDMS rubber
978-1-4673-1252-3
585-588
Freebody, N.A.
72208702-6768-40e3-8380-1c24ac69393a
Vaughan, A.S.
6d813b66-17f9-4864-9763-25a6d659d8a3
Lunt, P.J.B.
b3a5ee60-ef78-4b11-9ffe-ccbf87fd5751
Flavell, W.R.
cb73a8d5-86f5-430f-acfc-ca99becc48db
Wincott, P.L.
c4ca4a86-fffc-401e-b4f3-83ce6d2d1ed4
Freebody, N.A.
72208702-6768-40e3-8380-1c24ac69393a
Vaughan, A.S.
6d813b66-17f9-4864-9763-25a6d659d8a3
Lunt, P.J.B.
b3a5ee60-ef78-4b11-9ffe-ccbf87fd5751
Flavell, W.R.
cb73a8d5-86f5-430f-acfc-ca99becc48db
Wincott, P.L.
c4ca4a86-fffc-401e-b4f3-83ce6d2d1ed4

Freebody, N.A., Vaughan, A.S., Lunt, P.J.B., Flavell, W.R. and Wincott, P.L. (2012) The chemical analysis and replication of polydimethylsiloxane by-products located within electrical trees. 2012 IEEE Conference on Electrical Insulation and Dielectric Phenomena, Montreal, Canada. 14 - 17 Oct 2012. pp. 585-588 .

Record type: Conference or Workshop Item (Paper)

Abstract

We present a spectroscopic study of electrical trees grown in polydimethylesiloxane (PDMS) rubber. Electrical trees were grown at a range of voltages and allowed to propagate throughout the material. Breakdown and tree channels were exposed using cryogenic microtoming. Raman microprobe spectroscopy (RMS), Fourier Transform Infrared (FTIR), and X-ray Photoelectron Spectroscopy (XPS) were applied in order to obtain a detailed spectroscopic analysis of electrical treeing and breakdown in PDMS rubber.
For comparison, a selection of liquid systems including PDMS oil, dodecylbenzene (DDB) and dodecane (DD) were subjected to ageing via electrical discharges between two electrodes. The debris subsequently formed was subjected to spectroscopic analysis as before. Results are discussed in comparison to previously published results involving electrical treeing and corona discharge experiments in polyethylene (PE) and PDMS rubber

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More information

Published date: 14 October 2012
Venue - Dates: 2012 IEEE Conference on Electrical Insulation and Dielectric Phenomena, Montreal, Canada, 2012-10-14 - 2012-10-17
Organisations: EEE

Identifiers

Local EPrints ID: 344323
URI: http://eprints.soton.ac.uk/id/eprint/344323
ISBN: 978-1-4673-1252-3
PURE UUID: b02bf486-9425-47f3-ab4a-3d8db5d24c14
ORCID for A.S. Vaughan: ORCID iD orcid.org/0000-0002-0535-513X

Catalogue record

Date deposited: 18 Oct 2012 10:32
Last modified: 15 Mar 2024 03:05

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Contributors

Author: N.A. Freebody
Author: A.S. Vaughan ORCID iD
Author: P.J.B. Lunt
Author: W.R. Flavell
Author: P.L. Wincott

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