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Benzimidazole-based anion receptors exhibiting selectivity for lactate over pyruvate

Benzimidazole-based anion receptors exhibiting selectivity for lactate over pyruvate
Benzimidazole-based anion receptors exhibiting selectivity for lactate over pyruvate
The influence of anions on tautomerism in benzimidazole containing anion receptors has been studied via a variety of techniques in both solution and the solid state. The results show that hydrogen bonding interactions between the receptors and guests have a significant effect of the nature of the tautomer present. The compounds show a preference for complexation of lactate over pyruvate.



1477-0520
7780-7788
Hiscock, Jennifer R.
99a8a34c-a869-48e2-b713-1e69e4741032
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Lalaoui, Noémie
de13148e-a41e-42bf-bcd8-cd5e2d3f40b3
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Wells, Neil J.
86312185-007b-495b-86da-4e2e5b9b8025
Hiscock, Jennifer R.
99a8a34c-a869-48e2-b713-1e69e4741032
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Lalaoui, Noémie
de13148e-a41e-42bf-bcd8-cd5e2d3f40b3
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Wells, Neil J.
86312185-007b-495b-86da-4e2e5b9b8025

Hiscock, Jennifer R., Gale, Philip A., Lalaoui, Noémie, Light, Mark E. and Wells, Neil J. (2012) Benzimidazole-based anion receptors exhibiting selectivity for lactate over pyruvate. Organic & Biomolecular Chemistry, 10 (38), 7780-7788. (doi:10.1039/C2OB26299A).

Record type: Article

Abstract

The influence of anions on tautomerism in benzimidazole containing anion receptors has been studied via a variety of techniques in both solution and the solid state. The results show that hydrogen bonding interactions between the receptors and guests have a significant effect of the nature of the tautomer present. The compounds show a preference for complexation of lactate over pyruvate.



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e-pub ahead of print date: 9 August 2012
Published date: 14 October 2012
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 344380
URI: http://eprints.soton.ac.uk/id/eprint/344380
DOI: doi:10.1039/C2OB26299A
ISSN: 1477-0520
PURE UUID: a934e15d-88e8-463b-a033-21169e3c81e4
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843
ORCID for Neil J. Wells: ORCID iD orcid.org/0000-0002-4607-5791

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Date deposited: 22 Oct 2012 12:58
Last modified: 15 Mar 2024 03:06

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Contributors

Author: Jennifer R. Hiscock
Author: Philip A. Gale ORCID iD
Author: Noémie Lalaoui
Author: Mark E. Light ORCID iD
Author: Neil J. Wells ORCID iD

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