The University of Southampton
University of Southampton Institutional Repository

A HYSCORE investigation of bimetallic titanium–vanadium microporous catalysts: elucidating the nature of the active sites

A HYSCORE investigation of bimetallic titanium–vanadium microporous catalysts: elucidating the nature of the active sites
A HYSCORE investigation of bimetallic titanium–vanadium microporous catalysts: elucidating the nature of the active sites
Vanadium and titanium bimetallic AlPO-5 molecular sieves have been synthesized and characterized by means of Electron Spin Echo detected EPR and Hyperfine Sublevel Correlation (HYSCORE) spectroscopy. Direct evidence for framework substitution of redox-active Ti ions and VO2+ units at Al sites is provided through the detection of large P-31 hyperfine couplings.
1359-7345
8700-8702
Maurelli, Sara
a7b261b6-6687-4a5b-b2f3-7d6bbeebdc2d
Chiesa, Mario
848d9140-8756-4e2c-b15b-8f54d6ebab05
Giamello, Elio
ee77571e-0a2b-4c5c-9fd2-5d5d58bad97c
Leithall, Rebecca M.
01550709-ef72-44f1-8c73-eec71dc3a6b6
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Maurelli, Sara
a7b261b6-6687-4a5b-b2f3-7d6bbeebdc2d
Chiesa, Mario
848d9140-8756-4e2c-b15b-8f54d6ebab05
Giamello, Elio
ee77571e-0a2b-4c5c-9fd2-5d5d58bad97c
Leithall, Rebecca M.
01550709-ef72-44f1-8c73-eec71dc3a6b6
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b

Maurelli, Sara, Chiesa, Mario, Giamello, Elio, Leithall, Rebecca M. and Raja, Robert (2012) A HYSCORE investigation of bimetallic titanium–vanadium microporous catalysts: elucidating the nature of the active sites. Chemical Communications, 48 (69), 8700-8702. (doi:10.1039/c2cc33997h).

Record type: Article

Abstract

Vanadium and titanium bimetallic AlPO-5 molecular sieves have been synthesized and characterized by means of Electron Spin Echo detected EPR and Hyperfine Sublevel Correlation (HYSCORE) spectroscopy. Direct evidence for framework substitution of redox-active Ti ions and VO2+ units at Al sites is provided through the detection of large P-31 hyperfine couplings.

Full text not available from this repository.

More information

Published date: July 2012
Organisations: Chemistry

Identifiers

Local EPrints ID: 344392
URI: http://eprints.soton.ac.uk/id/eprint/344392
ISSN: 1359-7345
PURE UUID: 005c953c-6b2f-44b1-b88e-88ee69be227f
ORCID for Robert Raja: ORCID iD orcid.org/0000-0002-4161-7053

Catalogue record

Date deposited: 22 Oct 2012 15:02
Last modified: 18 Feb 2021 17:07

Export record

Altmetrics

Contributors

Author: Sara Maurelli
Author: Mario Chiesa
Author: Elio Giamello
Author: Rebecca M. Leithall
Author: Robert Raja ORCID iD

University divisions

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×