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Transition-metal versus heavy-metal synergy in selective catalytic oxidations

Transition-metal versus heavy-metal synergy in selective catalytic oxidations
Transition-metal versus heavy-metal synergy in selective catalytic oxidations
Simultaneous framework incorporation of heavy metal ions such as Ru(III) and Sn(IV) into aluminophosphate architectures generates novel bimetallic active sites, which facilitate synergistic interactions, affording high degrees of selectivity and activity in the catalytic oxidations, compared to analogous bimetallic systems, where transition-metals such as Co(III) and Ti(IV) have been similarly incorporated.
catalytic synergy, oxidation, microporous solids, redox catalysts, multifunctional active sites
2155-5435
2446-2451
Potter, Matthew
34dee7dc-2f62-4022-bb65-fc7b7fb526d2
Paterson, Alexander James
055bb1c5-e39b-46bd-8b28-12bd4aaa0f0d
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Potter, Matthew
34dee7dc-2f62-4022-bb65-fc7b7fb526d2
Paterson, Alexander James
055bb1c5-e39b-46bd-8b28-12bd4aaa0f0d
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b

Potter, Matthew, Paterson, Alexander James and Raja, Robert (2012) Transition-metal versus heavy-metal synergy in selective catalytic oxidations. ACS Catalysis, 2 (12), 2446-2451. (doi:10.1021/cs300404u).

Record type: Article

Abstract

Simultaneous framework incorporation of heavy metal ions such as Ru(III) and Sn(IV) into aluminophosphate architectures generates novel bimetallic active sites, which facilitate synergistic interactions, affording high degrees of selectivity and activity in the catalytic oxidations, compared to analogous bimetallic systems, where transition-metals such as Co(III) and Ti(IV) have been similarly incorporated.

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Published date: 19 October 2012
Keywords: catalytic synergy, oxidation, microporous solids, redox catalysts, multifunctional active sites
Organisations: Chemistry

Identifiers

Local EPrints ID: 344393
URI: http://eprints.soton.ac.uk/id/eprint/344393
ISSN: 2155-5435
PURE UUID: 238147d4-1d2a-4feb-8366-6a512277056e
ORCID for Matthew Potter: ORCID iD orcid.org/0000-0001-9849-3306
ORCID for Robert Raja: ORCID iD orcid.org/0000-0002-4161-7053

Catalogue record

Date deposited: 22 Oct 2012 15:14
Last modified: 18 Feb 2021 17:16

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