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{N,N?-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-?4N,N?,N??,N???}bis(trifluoromethanesulfanato-?O)copper(II)

{N,N?-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-?4N,N?,N??,N???}bis(trifluoromethanesulfanato-?O)copper(II)
{N,N?-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-?4N,N?,N??,N???}bis(trifluoromethanesulfanato-?O)copper(II)
A discrete neutral Cu(II) complex, [Cu(CF(3)SO(3))(2)(C(16)H(18)N(4))], has been derived from the symmetrical tetradentate Schiff base, N,N'-bis[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine. The copper centre assumes a tetragonally distorted pseudo-octahedral geometry with the O atoms of two trifluoromethanesulfonate anions coordinated weakly in the axial positions. The Cu-N distances lie in the range 1.941 (3)-2.011 (3) angstrom and the Cu-O distances are 2.474 (3) and 2.564 (3) angstrom.
m1435
Coles, S.J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Sengul, A.
91c75fc1-2342-4a2f-a4e0-f7b2d164c851
Kurt, O.
17dac737-5dac-4c72-82eb-6db314bb8560
Altin, S.
5ee8b823-df5d-484b-8a7b-d6f9ca2cdebb
Coles, S.J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Sengul, A.
91c75fc1-2342-4a2f-a4e0-f7b2d164c851
Kurt, O.
17dac737-5dac-4c72-82eb-6db314bb8560
Altin, S.
5ee8b823-df5d-484b-8a7b-d6f9ca2cdebb

Coles, S.J., Sengul, A., Kurt, O. and Altin, S. (2008) {N,N?-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-?4N,N?,N??,N???}bis(trifluoromethanesulfanato-?O)copper(II). Acta Crystallographica Section E: Structure Reports Online, 64 (11), m1435. (doi:10.1107/S1600536808033151).

Record type: Article

Abstract

A discrete neutral Cu(II) complex, [Cu(CF(3)SO(3))(2)(C(16)H(18)N(4))], has been derived from the symmetrical tetradentate Schiff base, N,N'-bis[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine. The copper centre assumes a tetragonally distorted pseudo-octahedral geometry with the O atoms of two trifluoromethanesulfonate anions coordinated weakly in the axial positions. The Cu-N distances lie in the range 1.941 (3)-2.011 (3) angstrom and the Cu-O distances are 2.474 (3) and 2.564 (3) angstrom.

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More information

Published date: November 2008
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 346480
URI: http://eprints.soton.ac.uk/id/eprint/346480
DOI: doi:10.1107/S1600536808033151
PURE UUID: 8aef20f4-ed31-4869-9693-3a91dd385eea
ORCID for S.J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

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Date deposited: 19 Dec 2012 16:51
Last modified: 15 Mar 2024 03:01

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Author: S.J. Coles ORCID iD
Author: A. Sengul
Author: O. Kurt
Author: S. Altin

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