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Enhancing solar cells with localized plasmons in nanovoids

Enhancing solar cells with localized plasmons in nanovoids
Enhancing solar cells with localized plasmons in nanovoids
Localized plasmon resonances of spherical nanovoid arrays strongly enhance solar cell performance by a factor of 3.5 in external quantum efficiency at plasmonic resonances, and a four-fold enhancement in overall power conversion efficiency. Large area substrates of silver nanovoids are electrochemically templated through self-assembled colloidal spheres and organic solar cells fabricated on top. Our design represents a new class of plasmonic photovoltaic enhancement: that of localized plasmon-enhanced absorption within nanovoid structures. Angularly-resolved spectra demonstrate strong localized Mie plasmon modes within the nanovoids. Theoretical modelling shows varied spatial dependence of light intensity within the void region suggesting a first possible route towards Third Generation plasmonic photovoltaics
1094-4087
11256-11263
Lal, N.N.
9b98140e-d6d6-4489-ada7-05bf0c9f8989
Soares, B.F.
89983b1e-0762-4343-b3f7-83e53ced4f36
Sinha, J.K.
6abb7840-e0b8-47a6-ad63-7dce6d1b7ce6
Huang, F.
da2bba71-decd-4d0a-9ba6-0ed12e1bd256
Mahajan, S.
b131f40a-479e-4432-b662-19d60d4069e9
Bartlett, P. N.
d99446db-a59d-4f89-96eb-f64b5d8bb075
Greenham, N. C.
fc8be32b-a4e3-4738-8cc5-8ae8992f3f92
Baumberg, J. J.
9c119632-1698-430f-bfb3-fa8ef0fdd134
Lal, N.N.
9b98140e-d6d6-4489-ada7-05bf0c9f8989
Soares, B.F.
89983b1e-0762-4343-b3f7-83e53ced4f36
Sinha, J.K.
6abb7840-e0b8-47a6-ad63-7dce6d1b7ce6
Huang, F.
da2bba71-decd-4d0a-9ba6-0ed12e1bd256
Mahajan, S.
b131f40a-479e-4432-b662-19d60d4069e9
Bartlett, P. N.
d99446db-a59d-4f89-96eb-f64b5d8bb075
Greenham, N. C.
fc8be32b-a4e3-4738-8cc5-8ae8992f3f92
Baumberg, J. J.
9c119632-1698-430f-bfb3-fa8ef0fdd134

Lal, N.N., Soares, B.F., Sinha, J.K., Huang, F., Mahajan, S., Bartlett, P. N., Greenham, N. C. and Baumberg, J. J. (2011) Enhancing solar cells with localized plasmons in nanovoids. Optics Express, 19 (12), 11256-11263. (doi:10.1364/OE.19.011256).

Record type: Article

Abstract

Localized plasmon resonances of spherical nanovoid arrays strongly enhance solar cell performance by a factor of 3.5 in external quantum efficiency at plasmonic resonances, and a four-fold enhancement in overall power conversion efficiency. Large area substrates of silver nanovoids are electrochemically templated through self-assembled colloidal spheres and organic solar cells fabricated on top. Our design represents a new class of plasmonic photovoltaic enhancement: that of localized plasmon-enhanced absorption within nanovoid structures. Angularly-resolved spectra demonstrate strong localized Mie plasmon modes within the nanovoids. Theoretical modelling shows varied spatial dependence of light intensity within the void region suggesting a first possible route towards Third Generation plasmonic photovoltaics

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Published date: June 2011

Identifiers

Local EPrints ID: 346823
URI: http://eprints.soton.ac.uk/id/eprint/346823
ISSN: 1094-4087
PURE UUID: 74b5c714-88d3-4e7e-9e05-13539cf1efcf
ORCID for S. Mahajan: ORCID iD orcid.org/0000-0001-8923-6666
ORCID for P. N. Bartlett: ORCID iD orcid.org/0000-0002-7300-6900

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Date deposited: 09 Jan 2013 14:48
Last modified: 15 Mar 2024 03:28

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Contributors

Author: N.N. Lal
Author: B.F. Soares
Author: J.K. Sinha
Author: F. Huang
Author: S. Mahajan ORCID iD
Author: P. N. Bartlett ORCID iD
Author: N. C. Greenham
Author: J. J. Baumberg

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