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The effect of film thickness on the suitability of titanium oxynitride (TiNxOy,x +y = 1) films as heat mirrors – formed by the atmospheric pressure CVD of TiCl4 and NH3

The effect of film thickness on the suitability of titanium oxynitride (TiNxOy,x +y = 1) films as heat mirrors – formed by the atmospheric pressure CVD of TiCl4 and NH3
The effect of film thickness on the suitability of titanium oxynitride (TiNxOy,x +y = 1) films as heat mirrors – formed by the atmospheric pressure CVD of TiCl4 and NH3
Films of titanium oxynitride are assessed for their potential as heat mirror coatings oil window glass, as a function of the film thickness. The coatings are deposited from the atmospheric pressure (AP) chemical vapor reaction of TiCl4 and ammonia. The heat mirror properties are evaluated using transmission and reflection spectroscopy. The composition of the samples is determined by X-ray photoelectron spectroscopy (XPS), and the thickness of the films by scanning electron microscopy (SEM). These results suggest that an effective heat mirror can be formed by a 100 nm thick coating of titanium oxynitride, which has a transmission of 49 % in the visible (6 10 nm), and a reflection of 46 % in the near infrared (1320 nm).
coatings, low-pressure cvd, titanium oxynitride
0948-1907
675-679
Hyett, G.
4f292fc9-2198-4b18-99b9-3c74e7dfed8d
Binions, R.
a2322a14-a7fa-44b2-bbd2-709e883fe42e
Parkin, I.P.
dad9ddcd-12a3-4365-b156-48eff153c48c
Hyett, G.
4f292fc9-2198-4b18-99b9-3c74e7dfed8d
Binions, R.
a2322a14-a7fa-44b2-bbd2-709e883fe42e
Parkin, I.P.
dad9ddcd-12a3-4365-b156-48eff153c48c

Hyett, G., Binions, R. and Parkin, I.P. (2007) The effect of film thickness on the suitability of titanium oxynitride (TiNxOy,x +y = 1) films as heat mirrors – formed by the atmospheric pressure CVD of TiCl4 and NH3. Chemical Vapor Deposition, 13 (12), 675-679. (doi:10.1002/cvde.200706638).

Record type: Article

Abstract

Films of titanium oxynitride are assessed for their potential as heat mirror coatings oil window glass, as a function of the film thickness. The coatings are deposited from the atmospheric pressure (AP) chemical vapor reaction of TiCl4 and ammonia. The heat mirror properties are evaluated using transmission and reflection spectroscopy. The composition of the samples is determined by X-ray photoelectron spectroscopy (XPS), and the thickness of the films by scanning electron microscopy (SEM). These results suggest that an effective heat mirror can be formed by a 100 nm thick coating of titanium oxynitride, which has a transmission of 49 % in the visible (6 10 nm), and a reflection of 46 % in the near infrared (1320 nm).

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e-pub ahead of print date: 7 December 2007
Published date: December 2007
Keywords: coatings, low-pressure cvd, titanium oxynitride
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 347000
URI: http://eprints.soton.ac.uk/id/eprint/347000
ISSN: 0948-1907
PURE UUID: a2b0a92d-cb8f-4b1f-b4f1-2acb834d0a19
ORCID for G. Hyett: ORCID iD orcid.org/0000-0001-9302-9723

Catalogue record

Date deposited: 14 Feb 2013 16:48
Last modified: 15 Mar 2024 03:45

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Contributors

Author: G. Hyett ORCID iD
Author: R. Binions
Author: I.P. Parkin

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