Alkylated organic cages: from porous crystals to neat liquids
Alkylated organic cages: from porous crystals to neat liquids
Rigid organic iminospherand cages are rendered meltable by multiple alkylation; below their melting points they can take the form of permanently porous crystals, crystals unstable to desolvation or nonporous glassy solids depending on chain length and branching; melting points as low as 50 degrees C are observed and a fully Newtonian liquid phase is obtained above 80 degrees C. Thin glassy fibres can be drawn out from a molten phase.
2153-2157
Giri, Nicola
73116700-c23c-439e-be0c-660d436409ff
Davidson, Christine E.
9c4e4db7-7b1f-41b5-88b4-4e947c983450
Melaugh, Gavin
ddff8283-a68d-46fc-9fa8-00d3c266f221
Del Pópolo, Mario G.
e2acde08-cdb9-4ce8-99ba-376012debd74
Jones, James T. A.
ff1f5fb6-a4e3-432c-8113-eba7d35d0c64
Hasell, Tom
6c8f5286-f4e2-456e-a3cd-dcfd3d164e52
Cooper, Andrew I.
95618a3b-7f3f-4731-a0d4-0a7b7ce07302
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
James, Stuart L.
64b3fff6-707c-4523-823b-e4890ed07b18
5 April 2012
Giri, Nicola
73116700-c23c-439e-be0c-660d436409ff
Davidson, Christine E.
9c4e4db7-7b1f-41b5-88b4-4e947c983450
Melaugh, Gavin
ddff8283-a68d-46fc-9fa8-00d3c266f221
Del Pópolo, Mario G.
e2acde08-cdb9-4ce8-99ba-376012debd74
Jones, James T. A.
ff1f5fb6-a4e3-432c-8113-eba7d35d0c64
Hasell, Tom
6c8f5286-f4e2-456e-a3cd-dcfd3d164e52
Cooper, Andrew I.
95618a3b-7f3f-4731-a0d4-0a7b7ce07302
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
James, Stuart L.
64b3fff6-707c-4523-823b-e4890ed07b18
Giri, Nicola, Davidson, Christine E., Melaugh, Gavin, Del Pópolo, Mario G., Jones, James T. A., Hasell, Tom, Cooper, Andrew I., Horton, Peter N., Hursthouse, Michael B. and James, Stuart L.
(2012)
Alkylated organic cages: from porous crystals to neat liquids.
Chemical Science, 3 (6), .
(doi:10.1039/c2sc01007k).
Abstract
Rigid organic iminospherand cages are rendered meltable by multiple alkylation; below their melting points they can take the form of permanently porous crystals, crystals unstable to desolvation or nonporous glassy solids depending on chain length and branching; melting points as low as 50 degrees C are observed and a fully Newtonian liquid phase is obtained above 80 degrees C. Thin glassy fibres can be drawn out from a molten phase.
This record has no associated files available for download.
More information
Published date: 5 April 2012
Organisations:
Organic Chemistry: Synthesis, Catalysis and Flow
Identifiers
Local EPrints ID: 347313
URI: http://eprints.soton.ac.uk/id/eprint/347313
ISSN: 1478-6524
PURE UUID: 0d9b946f-097c-4fe8-ba04-4748bad9c4f5
Catalogue record
Date deposited: 18 Jan 2013 11:31
Last modified: 15 Mar 2024 03:04
Export record
Altmetrics
Contributors
Author:
Nicola Giri
Author:
Christine E. Davidson
Author:
Gavin Melaugh
Author:
Mario G. Del Pópolo
Author:
James T. A. Jones
Author:
Tom Hasell
Author:
Andrew I. Cooper
Author:
Peter N. Horton
Author:
Stuart L. James
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics