Communication. Reactivity of phosphonodithioato-dppt NiII mixed ligand complexes with halogens: first example of a metal-coordinating tribromide anion
Communication. Reactivity of phosphonodithioato-dppt NiII mixed ligand complexes with halogens: first example of a metal-coordinating tribromide anion
The first example of a metal complex containing a tribromide anion is presented and characterised by X-ray diffraction. Hybrid DFT calculations were used to investigate the nature of the bond in coordinating trihalides and the differences with the corresponding mono-halide complexes.
6611-6613
Aragoni, M. Carla
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Arca, Massimiliano
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Coles, Susanne L.
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Devillanova, Francesco A.
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Hursthouse, Michael B.
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Isaia, Francesco
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Lippolis, Vito
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2012
Aragoni, M. Carla
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Arca, Massimiliano
f90b59f6-4dfb-471d-912e-3515e6507165
Coles, Susanne L.
b12334cf-6058-4a34-b409-81076d6c096f
Devillanova, Francesco A.
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Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Isaia, Francesco
11f997fe-81a3-4298-bbdc-15e5f2bf18cc
Lippolis, Vito
d9833a14-4aab-4827-a2ba-be818871dcf5
Aragoni, M. Carla, Arca, Massimiliano, Coles, Susanne L., Devillanova, Francesco A., Hursthouse, Michael B., Isaia, Francesco and Lippolis, Vito
(2012)
Communication. Reactivity of phosphonodithioato-dppt NiII mixed ligand complexes with halogens: first example of a metal-coordinating tribromide anion.
Dalton Transactions, 41 (22), .
(doi:10.1039/c2dt30540b).
Abstract
The first example of a metal complex containing a tribromide anion is presented and characterised by X-ray diffraction. Hybrid DFT calculations were used to investigate the nature of the bond in coordinating trihalides and the differences with the corresponding mono-halide complexes.
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e-pub ahead of print date: 17 April 2012
Published date: 2012
Organisations:
Organic Chemistry: Synthesis, Catalysis and Flow
Identifiers
Local EPrints ID: 347317
URI: http://eprints.soton.ac.uk/id/eprint/347317
ISSN: 0300-9246
PURE UUID: aefdb5c9-ed44-4948-874a-288ee4e85e41
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Date deposited: 21 Jan 2013 10:13
Last modified: 14 Mar 2024 12:46
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Contributors
Author:
M. Carla Aragoni
Author:
Massimiliano Arca
Author:
Susanne L. Coles
Author:
Francesco A. Devillanova
Author:
Francesco Isaia
Author:
Vito Lippolis
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