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Communication. Reactivity of phosphonodithioato-dppt NiII mixed ligand complexes with halogens: first example of a metal-coordinating tribromide anion

Communication. Reactivity of phosphonodithioato-dppt NiII mixed ligand complexes with halogens: first example of a metal-coordinating tribromide anion
Communication. Reactivity of phosphonodithioato-dppt NiII mixed ligand complexes with halogens: first example of a metal-coordinating tribromide anion
The first example of a metal complex containing a tribromide anion is presented and characterised by X-ray diffraction. Hybrid DFT calculations were used to investigate the nature of the bond in coordinating trihalides and the differences with the corresponding mono-halide complexes.
0300-9246
6611-6613
Aragoni, M. Carla
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Arca, Massimiliano
f90b59f6-4dfb-471d-912e-3515e6507165
Coles, Susanne L.
b12334cf-6058-4a34-b409-81076d6c096f
Devillanova, Francesco A.
a1015716-6d8a-4517-aac8-593b78e91561
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Isaia, Francesco
11f997fe-81a3-4298-bbdc-15e5f2bf18cc
Lippolis, Vito
d9833a14-4aab-4827-a2ba-be818871dcf5
Aragoni, M. Carla
3e73ed7a-2cf7-4f5e-9359-61d6e34a6cd5
Arca, Massimiliano
f90b59f6-4dfb-471d-912e-3515e6507165
Coles, Susanne L.
b12334cf-6058-4a34-b409-81076d6c096f
Devillanova, Francesco A.
a1015716-6d8a-4517-aac8-593b78e91561
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Isaia, Francesco
11f997fe-81a3-4298-bbdc-15e5f2bf18cc
Lippolis, Vito
d9833a14-4aab-4827-a2ba-be818871dcf5

Aragoni, M. Carla, Arca, Massimiliano, Coles, Susanne L., Devillanova, Francesco A., Hursthouse, Michael B., Isaia, Francesco and Lippolis, Vito (2012) Communication. Reactivity of phosphonodithioato-dppt NiII mixed ligand complexes with halogens: first example of a metal-coordinating tribromide anion. Dalton Transactions, 41 (22), 6611-6613. (doi:10.1039/c2dt30540b).

Record type: Article

Abstract

The first example of a metal complex containing a tribromide anion is presented and characterised by X-ray diffraction. Hybrid DFT calculations were used to investigate the nature of the bond in coordinating trihalides and the differences with the corresponding mono-halide complexes.

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e-pub ahead of print date: 17 April 2012
Published date: 2012
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 347317
URI: https://eprints.soton.ac.uk/id/eprint/347317
ISSN: 0300-9246
PURE UUID: aefdb5c9-ed44-4948-874a-288ee4e85e41

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Date deposited: 21 Jan 2013 10:13
Last modified: 18 Jul 2017 04:59

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