Beckett, Michael A., Horton, Peter N., Hursthouse, Michael B. and Timmis, James L. (2010) Bis(triphenylphosphoranylidene)ammonium iodide. Acta Crystallographica Section E: Structure Reports Online, 66 (2), o319-o319. (doi:10.1107/S1600536810000267).
Abstract
The title compound, C(36)H(30)NP(2)(+)center dot I(-), was obtained accidently from crystallization of a reaction mixture containing [(Ph(3)P)(2)N]OH and B(OH)(3), which was contaminated with MeI. There are two independent [(Ph(3)P)(2)N](+) cations and two I(-) anions within the asymmetric unit. The central PNP angles are non-linear [137.6 (2) and 134.4 (2)degrees] and the phenyl substituents on P centres adopt different conformations within these two cations.
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- Faculties (pre 2018 reorg) > Faculty of Natural and Environmental Sciences (pre 2018 reorg) > Chemistry (pre 2018 reorg) > Organic Chemistry - Synthesis, Catalysis and Flow (pre 2018 reorg)
Current Faculties > Faculty of Engineering and Physical Sciences > School of Chemistry > Chemistry (pre 2018 reorg) > Organic Chemistry - Synthesis, Catalysis and Flow (pre 2018 reorg)
School of Chemistry > Chemistry (pre 2018 reorg) > Organic Chemistry - Synthesis, Catalysis and Flow (pre 2018 reorg) - Faculties (pre 2018 reorg) > Faculty of Natural and Environmental Sciences (pre 2018 reorg) > Chemistry (pre 2018 reorg)
Current Faculties > Faculty of Engineering and Physical Sciences > School of Chemistry > Chemistry (pre 2018 reorg)
School of Chemistry > Chemistry (pre 2018 reorg)
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