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Tetraphenylboroxinate(1-) salts of monoborate cations: Synthesis and single-crystal X-ray structures of [Ph2B{OCH2CH2N(Me)(CH2)n}2][Ph4B3O3] (n=4, 5)

Tetraphenylboroxinate(1-) salts of monoborate cations: Synthesis and single-crystal X-ray structures of [Ph2B{OCH2CH2N(Me)(CH2)n}2][Ph4B3O3] (n=4, 5)
Tetraphenylboroxinate(1-) salts of monoborate cations: Synthesis and single-crystal X-ray structures of [Ph2B{OCH2CH2N(Me)(CH2)n}2][Ph4B3O3] (n=4, 5)
The salts, [Ph(2)B{OCH(2)CH(2)N(Me)(CH(2))(n)}(2)][Ph(4)B(3)O(3)](n = 4,5), were prepared in moderate yields in MeOH solution from reaction of Ph(2)BOBPh(2) with [N(CH(2))n(Me)(CH(2)CH(2)OH)][OH] and PhB(OH)(2) in a 1:2:4 ratio. The reactions also lead to Ph(3)B(3)O(3). Both salts were characterized by NMR ((1)H, (13)C, (11)B) IR, and single-crystal XRD studies. The salts are comprised of cationic monoborates (zwitterionic, 2N(+) and 1B(-)) and tetraphenylboroxinate anions. (C) 2009 Elsevier B.V. All rights reserved
0022-328X
1080-1083
Beckett, Michael A.
5b021ef6-fa5c-4f6d-9998-3313558f0dc1
Bennett, Elliot L.
945565d0-1913-4f09-b6e8-acffb12d8f0c
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Beckett, Michael A.
5b021ef6-fa5c-4f6d-9998-3313558f0dc1
Bennett, Elliot L.
945565d0-1913-4f09-b6e8-acffb12d8f0c
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Beckett, Michael A., Bennett, Elliot L., Horton, Peter N. and Hursthouse, Michael B. (2010) Tetraphenylboroxinate(1-) salts of monoborate cations: Synthesis and single-crystal X-ray structures of [Ph2B{OCH2CH2N(Me)(CH2)n}2][Ph4B3O3] (n=4, 5). Journal of Organometallic Chemistry, 695 (7), 1080-1083. (doi:10.1016/j.jorganchem.2009.09.026).

Record type: Article

Abstract

The salts, [Ph(2)B{OCH(2)CH(2)N(Me)(CH(2))(n)}(2)][Ph(4)B(3)O(3)](n = 4,5), were prepared in moderate yields in MeOH solution from reaction of Ph(2)BOBPh(2) with [N(CH(2))n(Me)(CH(2)CH(2)OH)][OH] and PhB(OH)(2) in a 1:2:4 ratio. The reactions also lead to Ph(3)B(3)O(3). Both salts were characterized by NMR ((1)H, (13)C, (11)B) IR, and single-crystal XRD studies. The salts are comprised of cationic monoborates (zwitterionic, 2N(+) and 1B(-)) and tetraphenylboroxinate anions. (C) 2009 Elsevier B.V. All rights reserved

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More information

Published date: 1 April 2010
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 347478
URI: https://eprints.soton.ac.uk/id/eprint/347478
ISSN: 0022-328X
PURE UUID: 9da2e6b6-7248-492b-9348-4d0fc666e7b1
ORCID for Peter N. Horton: ORCID iD orcid.org/0000-0001-8886-2016

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Date deposited: 24 Jan 2013 14:17
Last modified: 06 Jun 2018 12:52

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